Alkali activated materials vs geopolymers: Role of boron as an eco-friendly replacement

2017 ◽  
Vol 146 ◽  
pp. 297-302 ◽  
Author(s):  
Ali Bagheri ◽  
Ali Nazari ◽  
Jay G. Sanjayan ◽  
Pathmanathan Rajeev
Keyword(s):  
1994 ◽  
Vol 370 ◽  
Author(s):  
A.R. Brough ◽  
A. Katz ◽  
T. Bakharev ◽  
G-.K. Sun ◽  
R.J. Kirkpatrick ◽  
...  

AbstractWasteforms made by reaction at elevated temperature of a highly alkaline simulated low-level nuclear waste solution, having high sodium ion concentration, with a cementitious blend high in fly ash have been studied. Significant formation of Na-P1 zeolite (gismondine framework) and of a sodalite occurred. The time evolution of the crystalline phases over the first 28 days is reported for both adiabatic and isothermal curing, and the role of these phases in microstructure development is discussed. The level of carbonate ions in solution was found to have a substantial effect on strength evolution and chemistry.


2020 ◽  
Vol 4 ◽  
pp. 110-121 ◽  
Author(s):  
Claire White

Alternative (i.e., non-Portland) cements, such as alkali-activated materials, have gained significant interest from the scientific community due to their proven CO2 savings compared with Portland cement together with known short-term performance properties. However, the concrete industry remains dominated by Portland cement-based concrete. This Letter explores the technical and non-technical hurdles preventing implementation of an alternative cement, such as alkali-activated materials, in the concrete industry and discusses how these hurdles can be overcome. Specifically, it is shown that certain technical hurdles, such as a lack of understanding how certain additives affect setting of alkali-activated materials (and Portland cement) and the absence of long-term in-field performance data of these sustainable cements, can be mitigated via the use of key molecular- and nano-scale experimental techniques to elucidate dominant material characteristics, including those that control long-term performance. In the second part of this Letter the concrete industry is compared and contrasted with the electricity generation industry, and specifically the transition from one dominant technology (i.e., coal) to a diverse array of energy sources including renewables. It is concluded that financial incentives and public advocacy (akin to advocacy for renewables in the energy sector) would significantly enhance uptake of alternative cements in the concrete industry.


2014 ◽  
Vol 48 (3) ◽  
pp. 585-597 ◽  
Author(s):  
I. García-Lodeiro ◽  
N. Cherfa ◽  
F. Zibouche ◽  
A. Fernández-Jimenez ◽  
A. Palomo
Keyword(s):  

2014 ◽  
Vol 53 (10-11) ◽  
pp. 843-855 ◽  
Author(s):  
Kirk Vance ◽  
Akash Dakhane ◽  
Gaurav Sant ◽  
Narayanan Neithalath

Materials ◽  
2021 ◽  
Vol 14 (8) ◽  
pp. 1918
Author(s):  
Marija Nedeljković ◽  
Bahman Ghiassi ◽  
Guang Ye

Understanding the role of curing conditions on the microstructure and phase chemistry of alkali-activated materials (AAMs) is essential for the evaluation of the long-term performance as well as the optimization of the processing methods for achieving more durable AAMs-based concretes. However, this information cannot be obtained with the common material characterization techniques as they often deliver limited information on the chemical domains and proportions of reaction products. This paper presents the use of PhAse Recognition and Characterization (PARC) software to overcome this obstacle for the first time. A single precursor (ground granulated blast-furnace slag (GBFS)) and a binary precursor (50% GBFS–50% fly ash) alkali-activated paste are investigated. The pastes are prepared and then cured in sealed and unsealed conditions for up to one year. The development of the microstructure and phase chemistry are investigated with PARC, and the obtained results are compared with independent bulk analytical techniques X-ray Powder Fluorescence and X-ray Powder Diffraction. PARC allowed the determination of the type of reaction products and GBFS and FA’s spatial distribution and degree of reaction at different curing ages and conditions. The results showed that the pastes react at different rates with the dominant reaction products of Mg-rich gel around GBFS particles, i.e., Ca-Mg-Na-Al-Si, and with Ca-Na-Al-Si gel, in the bulk paste. The microstructure evolution was significantly affected in the unsealed curing conditions due to the Na+ loss. The effect of the curing conditions was more pronounced in the binary system.


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