A novel integrated structure of hydrogen purification and liquefaction using natural gas steam reforming, organic Rankine cycle and photovoltaic panels

Cryogenics ◽  
2021 ◽  
Vol 119 ◽  
pp. 103352
Author(s):  
Bahram Ghorbani ◽  
Mehdi Mehrpooya ◽  
Majid Amidpour
Author(s):  
Abdullah Al-Abdulkarem ◽  
Yunho Hwang ◽  
Reinhard Radermacher

Although natural gas is considered as a clean fuel compared to coal, natural gas combined cycles (NGCC) emit high amounts of CO2 at the plant site. To mitigate global warming caused by the increase in atmospheric CO2, CO2 capture and sequestration (CCS) using amine absorption is proposed. However, implementing this CCS system increases the energy consumption by about 15–20%. Innovative processes integration and waste heat utilization can be used to improve the energy efficiency. Four waste heat sources and five potential uses were uncovered and compared using a parameter defined as the ratio of power gain to waste heat. A new integrated CCS configuration is proposed, which integrates the NGCC with the CO2 removal and CO2 compression cycles. HYSYS simulation software was used to simulate the CO2 removal cycle using monoethanolamine (MEA) solution, NGCC, CO2 compression cycle, CO2 liquefaction cycles and Organic Rankine Cycle (ORC). The developed models were validated against experimental data from the literature with good agreements. Two NGCC with steam extraction configurations were optimized using Matlab GA tool coupled with HYSYS simulation software. Efficiency improvement in one of the proposed CCS configurations that uses the available waste heat in absorption chillers to cool the inlet-air to the gas turbine and to run an ORC, and uses the developed CO2 liquefaction and pumping instead of multistage compression is 6.04 percent point, which represents 25.91 MW more power than the conventional CCS configuration.


Author(s):  
M. Bianchi ◽  
L. Branchini ◽  
A. De Pascale ◽  
F. Melino ◽  
V. Orlandini ◽  
...  

Gas compressor stations represent a huge potential for exhaust heat recovery. Typical installations consist of open cycle configurations with multiple gas turbine units, usually operated under part-load conditions during the year with limited conversion efficiency. At least, one of the installed unit serves as back-up to ensure the necessary reserve power and the safe operation of the station. Organic Rankine Cycle (ORC) has been proven as an economical and environmentally friendly solution to recover waste heat from gas turbines, improving the overall energy system performance and reducing the CO2 emissions. In this context, taking as reference typical gas compressor stations located in North America, the paper investigates the potential benefit of ORC application, as bottomer section of gas turbines, in natural gas compression facilities. Thus, ORC converts gas turbines wasted heat into useful additional power that can be used inside the compression facility reducing the amount of consumed natural gas and, consequently, the environmental emissions, or directed to the grid, thus furthermore earning economic benefits. Different case studies are examined with reference to two typical compressor station size ranges: a “small-medium” and a “medium-high” size range. Two different gas turbine models are considered according to most common manufacturers. Typical gas compressor stations and integrated cycle configurations are identified. Based on Turboden experience in development and production of ORCs, specific design options and constraints, layout arrangements and operating parameters are examined and compared in this study, such as the use of an intermediate heat transfer fluid, the type of organic fluid, the influence of superheating degree and condensation temperature values. Emphasis is given on thermodynamic performance of the integrated system by evaluating thermal energy and mechanical power recovery. Several key performance indexes are defined such as, the ORC power and efficiency, the specific power recovery per unit of compression power, the integrated system net overall power output and efficiency, the ORC expander and heat exchangers size parameters, the carbon emission savings, etc. The performed comparison of various configurations shows that: (i) the energy recovery with ORC can be remarkable, adding up to more than 35% of additional shaft power to the compression station in the best configuration; (ii) the ORC condensation temperature value has a significant impact on the ORC bottomer cycle and on the integrated system performance; (iii) in case of Cyclopentane, keeping the same ORC cycle operating parameters, the max specific power recovery is achieved in the direct configuration case, (iv) the bottomer cycle size can be reduced with the use of a refrigerant fluid (R1233zd(E)), compared to hydrocarbon fluids; (v) the max environmental benefit can be up to 120 kg CO2/h saved per MW of installed compression power.


2006 ◽  
Vol 129 (2) ◽  
pp. 338-351 ◽  
Author(s):  
Alessandro Corradetti ◽  
Umberto Desideri

Steam methane reforming is the most common process for producing hydrogen in the world. It currently represents the most efficient and mature technology for this purpose. However, because of the high investment costs, this technology is only convenient for large sizes. Furthermore, the cooling of syngas and flue gas produce a great amount of excess steam, which is usually transferred outside the process, for heating purposes or industrial applications. The opportunity of using this additional steam to generate electric power has been studied in this paper. In particular, different power plant schemes have been analyzed, including (i) a Rankine cycle, (ii) a gas turbine simple cycle, and (iii) a gas-steam combined cycle. These configurations have been investigated with the additional feature of CO2 capture and sequestration. The reference plant has been modeled according to state-of-the-art of commercial hydrogen plants: it includes a prereforming reactor, two shift reactors, and a pressure swing adsorption unit for hydrogen purification. The plant has a conversion efficiency of ∼75% and produces 145,000Sm3∕hr of hydrogen (equivalent to 435MW on the lower-heating-volume basis) and 63t∕hr of superheated steam. The proposed power plants generate, respectively, 22MW (i), 36MW (ii), and 87MW (iii) without CO2 capture. A sensitivity analysis was carried out to determine the optimum size for each configuration and to investigate the influence of some parameters, such as electricity, natural gas, and steam costs.


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