Decoupled ion conduction mechanism of poly(vinyl alcohol) based Mg-conducting solid polymer electrolyte

2006 ◽  
Vol 52 (4) ◽  
pp. 1549-1555 ◽  
Author(s):  
Soo-Kyeong Jeong ◽  
Yun-Kyung Jo ◽  
Nam-Ju Jo
Keyword(s):  
Polymer Electrolyte ◽  
Vinyl Alcohol ◽  
Solid Polymer Electrolyte ◽  
Conduction Mechanism ◽  
Solid Polymer ◽  
Poly Vinyl Alcohol ◽  
Ion Conduction ◽  
Ion Conduction Mechanism

Investigation of Electrical Properties, Structure and Morphological Characterization of Mg+2 Ions Conducting Solid Polymer Electrolyte Based on Poly(vinyl alcohol)

2017 ◽  
Vol 6 (1) ◽  
pp. 102-107 ◽  
Author(s):  
Reda Khalil ◽  
Eslam Mohamed Sheha ◽  
Alaa Eid
Keyword(s):  
Polymer Electrolyte ◽  
Vinyl Alcohol ◽  
Solid Polymer Electrolyte ◽  
Transference Number ◽  
Morphological Characterization ◽  
Solid Polymer ◽  
Poly Vinyl Alcohol ◽  
Casting Technique ◽  
Ionic Transference Number ◽  
Electrolyte Component

In the present work, solid polymer electrolyte using poly(vinyl alcohol) (PVA) and magnesium perchlorate (Mg(ClO4)2) in different compositions has been prepared by the solution-casting technique method. Surface feature of films was characterized by scanning electron microscopy (SEM) measurement. X-ray diffraction (XRD) was used to determine the complexation of the polymer with the salt. The electrophysical characteristics were measured and analyzed as dependent on the concentration, nature of the solid polymer electrolyte component and ambient temperature. A maximum ionic conductivity value of ∼10–4 S/cm at 303 K is obtained for PVA0.6/(Mg(ClO4)2)0.4 composite. The ionic transference number of Mg+2 mobile ions has been estimated by a dc polarization method. The result reveals that the conducting species are predominantly ions.

Synthesis and characterization of solid polymer electrolyte based on poly(vinyl alcohol)/gum Arabic/LiClO4

Ionics ◽  
2020 ◽  
Vol 26 (6) ◽  
pp. 2941-2948 ◽  
Author(s):  
Camila M. Cholant ◽  
Luana U. Krüger ◽  
Raphael D. C Balboni ◽  
Marco P. Rodrigues ◽  
Fabiele C. Tavares ◽  
...  
Keyword(s):  
Polymer Electrolyte ◽  
Vinyl Alcohol ◽  
Solid Polymer Electrolyte ◽  
Gum Arabic ◽  
Solid Polymer ◽  
Synthesis And Characterization ◽  
Poly Vinyl Alcohol

Swapping conventional salts with an entrapped lithiated anionic polymer: fast single-ion conduction and electrolyte feasibility in LiFePO4/Li batteries

2017 ◽  
Vol 5 (24) ◽  
pp. 12202-12215 ◽  
Author(s):  
Soujanya Gowneni ◽  
Pratyay Basak
Keyword(s):  
Polymer Electrolyte ◽  
Solid Polymer Electrolyte ◽  
Solid Polymer ◽  
Anionic Polymer ◽  
Ion Conduction ◽  
New Class ◽  
Li Batteries

Herein, we report on a new class of quasi-solid polymer electrolyte matrix that supports appreciably fast single-ion conduction.

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