Thermal Aging of Anions in Ionic Liquids containing Lithium Salts by IC/ESI-MS

The current theoretical study explains the difference in solubility between lithium and sodium salts in ionic liquids due to increased covalency in lithium salts.

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Physicochemical and Electrochemical Properties of Novel Ionic Liquids Containing Aprotic Heterocyclic Anions Doped with Lithium Salts

ECS Meeting Abstracts ◽

10.1149/ma2012-02/53/3626 ◽

2012 ◽

Keyword(s):

Ionic Liquids ◽

Electrochemical Properties ◽

Lithium Salts

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Pyrrolidinium-Based Ionic Liquids Doped with Lithium Salts: How Does Li+ Coordination Affect Its Diffusivity?

The Journal of Physical Chemistry B ◽

10.1021/jp509387r ◽

2014 ◽

Vol 118 (47) ◽

pp. 13679-13688 ◽

Cited By ~ 38

Author(s):

Franca Castiglione ◽

Antonino Famulari ◽

Guido Raos ◽

Stefano V. Meille ◽

Andrea Mele ◽

...

Keyword(s):

Ionic Liquids ◽

Lithium Salts

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Effect of Nitrile-Functionalization of Imidazolium-Based Ionic Liquids on Their Transport Properties, Both Pure and Mixed with Lithium Salts

Journal of Solution Chemistry ◽

10.1007/s10953-014-0280-2 ◽

2014 ◽

Vol 44 (3-4) ◽

pp. 495-510 ◽

Cited By ~ 5

Author(s):

Hassan Srour ◽

Mounir Traïkia ◽

Bernard Fenet ◽

Hélène Rouault ◽

Margarida F. Costa Gomes ◽

...

Keyword(s):

Ionic Liquids ◽

Transport Properties ◽

Lithium Salts

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Molecular dynamics analysis of the effect of electronic polarization on the structure and single-particle dynamics of mixtures of ionic liquids and lithium salts

The Journal of Chemical Physics ◽

10.1063/1.4968393 ◽

2016 ◽

Vol 145 (20) ◽

pp. 204507 ◽

Cited By ~ 14

Author(s):

Volker Lesch ◽

Hadrián Montes-Campos ◽

Trinidad Méndez-Morales ◽

Luis Javier Gallego ◽

Andreas Heuer ◽

...

Keyword(s):

Molecular Dynamics ◽

Ionic Liquids ◽

Single Particle ◽

Particle Dynamics ◽

Lithium Salts ◽

Dynamics Analysis ◽

Electronic Polarization

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Solvation of Lithium Salts in Protic Ionic Liquids: A Molecular Dynamics Study

The Journal of Physical Chemistry B ◽

10.1021/jp410090f ◽

2014 ◽

Vol 118 (3) ◽

pp. 761-770 ◽

Cited By ~ 62

Author(s):

Trinidad Méndez-Morales ◽

Jesús Carrete ◽

Óscar Cabeza ◽

Olga Russina ◽

Alessandro Triolo ◽

...

Keyword(s):

Molecular Dynamics ◽

Ionic Liquids ◽

Lithium Salts ◽

Protic Ionic Liquids

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Efficient CO2 capture by tertiary amine-functionalized ionic liquids through Li+-stabilized zwitterionic adduct formation

Beilstein Journal of Organic Chemistry ◽

10.3762/bjoc.10.204 ◽

2014 ◽

Vol 10 ◽

pp. 1959-1966 ◽

Cited By ~ 20

Author(s):

Zhen-Zhen Yang ◽

Liang-Nian He

Keyword(s):

Ionic Liquids ◽

Co2 Capture ◽

Tertiary Amine ◽

Adduct Formation ◽

Lithium Salts ◽

Organic Base ◽

Organic Bases ◽

Amine Functionalized ◽

Neutral Ligands ◽

Cation Coordination

Highly efficient CO2 absorption was realized through formation of zwitterionic adducts, combining synthetic strategies to ionic liquids (ILs) and coordination. The essence of our strategy is to make use of multidentate cation coordination between Li+ and an organic base. Also PEG-functionalized organic bases were employed to enhance the CO2-philicity. The ILs were reacted with CO2 to form the zwitterionic adduct. Coordination effects between various lithium salts and neutral ligands, as well as the CO2 capacity of the chelated ILs obtained were investigated. For example, the CO2 capacity of PEG150MeBu2N increased steadily from 0.10 to 0.66 (mol CO2 absorbed per mol of base) through the formation of zwitterionic adducts being stabilized by Li+.

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