Color Changes and Mechanical Properties of Glass Fiber Reinforced Polycarbonate Composites after Thermal Aging

Thermal aging of polymer matrix composites exert significant influence on their properties and applications. This paper studied the color changes and mechanical properties of glass fiber reinforced polycarbonate (GF-PC) composites after aging at different temperatures, and the correlation between the trend of color changes and mechanical properties after aging was discussed. The GF-PC composites were aged at 85 °C, 100 °C, 115 °C, 130 °C and 145 °C, respectively. Thereafter, CIELAB colors were used to characterize the color changes of the composites after aging. Tensile and three-point bending tests were carried out to determine the mechanical properties of the composites. According to the values of CIELAB color, the color changes and the color difference (ΔE) of the GF-PC composites after aging were calculated, which showed that color of the GF-PC composite aged at 100 °C changed the most. The color changes of the composites after aging mainly comes from the change of brightness (L value), which was 25.067 for the Raw GF-PC composite. When the aging temperature increased from 85 °C to 100 °C, the brightness of the composites also increased, but decreased when the aging temperature is above 100 °C and continues to rise. Coincidentally, the trend of the mechanical properties of GF-PC composites is closely associated with color changes in the aging temperature range of 85 °C to 145 °C. The tensile and flexural strength of the composites reached the maximum value 72 MPa and 131 MPa, respectively, after aged at 100 °C. It can be speculated that the brightness of the GF-PC composites correlates with trends observed in its tensile strength and bending strength.

Analysis of XLPE cable parameters subject to thermo aging

Modern marine vessels use electrically driven rudders; cruise liners, gas carriers, tankers are equipped with Azipod systems manufactured by the Swedish-Swiss company ABB. Gondola-type propellers make it possible to break ice when the vessel is moving astern, therefore such vessels are used for work on the Northern Sea Route, in particular, when working on the Yamal LNG project. The 22MW Azipod propulsion system rotates 360° and enables difficult maneuvering without the assistance of tugs. When operating such propellers, powerful diesel generators are installed on the ship. For the transmission of electricity, ship cables are used, which are subject to increased requirements that meet the standard of the International Electrotechnical Commission. Modern marine vessels are equipped with XLPE or EPDM insulated cable lines; industrial production of these cables is carried out in the Russian Federation. In the course of the study, a method for auditing the state of insulation has been considered based on an assessment of the change in the tangent of the angle of dielectric losses in the process of thermal aging of the cable of the PvBPng(A)-HF brand. Measurements of the tangent of the dielectric losses' angle have been carried out with a Tangens-2000 insulation parameter meter.

Pre-Breakdown and Breakdown Behavior of Synthetic and Natural Ester Liquids under AC Stress

In the last decades, a large focus is being placed on the sustainability and safety of the power transformer spectrum. Ester liquids, which have interesting properties such as high fire point and biodegradability, are gaining needed attraction. Since in-service condition, thermal aging deteriorates the physicochemical and electrical properties of liquid dielectrics, it is important to study their long-term behavior. In this contribution, the pre-breakdown and breakdown behavior of ester fluids (synthetic and natural) under AC stress are investigated. Important characteristics, such as partial discharge pre-inception voltage, partial discharge inception voltage, breakdown voltage, average streamer velocity, and inception electric field, were assessed. The influence of the radius of curvature (of high voltage needle electrode) as well as the thermal degradation of typical ester liquids are also discussed. Mineral oil was also included in the tests loop as a benchmark for comparative purposes. It is found that the pre-inception voltage of ester liquids was, in most cases, higher than that of mineral oil. For a given radius of curvature, the streamer inception and breakdown voltages decreased with thermal aging. During the streamer initiation, the electric field at the electrode tip decreased with the increase in the radius of curvature. The velocity of the streamers seems to increase with the decrease in the radius of curvature. The period of vulnerability, the so-called “delay time”, seems to be independent of the aging or the radius of curvature for a given condition of the liquid.

Effect of Thermal Aging on Mechanical Properties and Color Difference of Glass Fiber/Polyetherimide (GF/PEI) Composites

This research study is aimed at evaluating the mechanical characteristics in terms of tensile strength and flexural strength of glass fiber reinforced Polyetherimide (GF/PEI) under different thermal aging. Tensile testing and bending testing were performed on the thermally aged polyetherimide composites. The mechanical properties of the thermally aged samples were also correlated with their color difference. The experimental results showed that both the tensile strength and flexural strength of the GF/PEI composite samples decreased with increasing aging temperature. However, the elastic modulus of the composite samples is nearly independent on the thermal aging. The thermally aged samples exhibited brittle fracture, resulting in low strength and low ductility. The loss in strength after thermal aging could be also linked to the change of their color difference, which can indirectly reflect the change of the strength for the composites after thermal aging.