Mean-Field Theory of Electrical Double Layer In Ionic Liquids with Account of Short-Range Correlations

2017 ◽  
Vol 225 ◽  
pp. 190-197 ◽  
Author(s):  
Zachary A.H. Goodwin ◽  
Guang Feng ◽  
Alexei A. Kornyshev
Keyword(s):  
Field Theory ◽  
Ionic Liquids ◽  
Double Layer ◽  
Electrical Double Layer ◽  
Short Range ◽  
Mean Field Theory ◽  
Mean Field ◽  
Short Range Correlations

Mean-Field Theory of the Electrical Double Layer in Ionic Liquids

2021 ◽  
pp. 1-13
Author(s):  
Zachary A. H. Goodwin ◽  
J. Pedro de Souza ◽  
Martin Z. Bazant ◽  
Alexei A. Kornyshev
Keyword(s):  
Field Theory ◽  
Ionic Liquids ◽  
Double Layer ◽  
Electrical Double Layer ◽  
Mean Field Theory ◽  
Mean Field

Transitions de phase dans une couche monomoléculaire sur un substrat liquide adhésif

1975 ◽  
Vol 53 (21) ◽  
pp. 2369-2374 ◽  
Author(s):  
Alain Caillé ◽  
Göran Ågren
Keyword(s):  
Field Theory ◽  
Nematic Phase ◽  
Short Range ◽  
Mean Field Theory ◽  
Mean Field ◽  
Isotropic Phase ◽  
Minimum Length ◽  
Monomolecular Layer ◽  
Short Range Repulsion ◽  
Breadth Ratio

We use a lattice model to characterize the state of a monomolecular layer of long and rigid molecules. The solutions are obtained using a mean field theory with only short range repulsion forces. The basic results are: (1) a stable nematic phase for a region of density above a minimum length to breadth ratio; (2) the transition between the nematic phase and the isotropic phase is found to be second order. The results are in excellent agreement with those obtained with a mercury subphase.

Critical Wetting with Short-Range Forces: Is Mean-Field Theory Valid?

1986 ◽  
Vol 56 (21) ◽  
pp. 2272-2275 ◽  
Author(s):  
K. Binder ◽  
D. P. Landau ◽  
D. M. Kroll
Keyword(s):  
Field Theory ◽  
Short Range ◽  
Mean Field Theory ◽  
Mean Field ◽  
Critical Wetting

Differential capacitance of an electric double layer with asymmetric solvent-mediated interactions: mean-field theory and Monte Carlo simulations

2017 ◽  
Vol 19 (35) ◽  
pp. 23971-23981 ◽  
Author(s):  
Daniel L. Z. Caetano ◽  
Guilherme V. Bossa ◽  
Vinicius M. de Oliveira ◽  
Matthew A. Brown ◽  
Sidney J. de Carvalho ◽  
...  
Keyword(s):  
Field Theory ◽  
Monte Carlo ◽  
Double Layer ◽  
Electrolyte Solution ◽  
Electric Double Layer ◽  
Mean Field Theory ◽  
Mean Field ◽  
Differential Capacitance ◽  
Solvent Structure ◽  
Ionic Size

The differential capacitance of an electrical double layer is directly affected by properties of the electrolyte solution such as temperature, salt concentration, ionic size, and solvent structure.

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