Numerical study on laminar burning velocity and ignition delay time of ammonia flame with hydrogen addition

Energy ◽  
2017 ◽  
Vol 126 ◽  
pp. 796-809 ◽  
Author(s):  
Jun Li ◽  
Hongyu Huang ◽  
Noriyuki Kobayashi ◽  
Chenguang Wang ◽  
Haoran Yuan
Energies ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3562
Author(s):  
Fekadu Mosisa Wako ◽  
Gianmaria Pio ◽  
Ernesto Salzano

The need for lowering the environmental impacts has incentivized the investigation of biomass and biofuels as possible alternative sources for energy supply. Among the others, oxygenated bio-derived molecules such as alcohols, esters, acids, aldehydes, and furans are attractive substances as chemical feedstock and for sustainable energy production. Indeed, the presence of oxygen atoms limits the production of aromatic compounds, improves combustion efficiency (thus heat production) and alleviates the formation of carbon soot. On the other hand, the variability of their composition has represented one of the major challenges for the complete characterization of combustion behaviour. This work gives an overview of the current understanding of the detailed chemical mechanisms, as well as experimental investigations characterizing the combustion process of these species, with an emphasis on the laminar burning velocity and the ignition delay time. From the review, the common intermediates for the most relevant functional groups and combustion of biofuels were identified. The gathered information can be intended for the sake of core mechanism generation.


Author(s):  
Nguyen Minh Tien Nguyen

This study presents the effect of ignition energy (Eig) on ignition delay time (tdelay) and uncertainty of laminar burning velocity (Su0) measurement of lean methane/air mixture in a constant volume combustion chamber. The mixture at an equivalence ratio of 0.6 is ignited using a pair of electrodes at the 2-mm spark gap. Eig is measured by integrating the product of voltage V(t) and current I(t) signals during a discharge period. The in-chamber pressure profiles are analyzed using the pressure-rise method to obtain tdelay and Su0. Su0 approximates 8.0 cm/s. Furthermore, the increasing Eig could shorten tdelay, leading to a faster combustion process. However, when Eig is greater than a critical value, called minimum reliable ignition energy (MRIE), the additional elevating Eig has the marginal effect on tdelay and Su0. The existence of MRIE supports to optimize the ignition systems and partly explains why extreme-high Eig>> MRIE has less contribution to engine performance.


Author(s):  
Olivier Mathieu ◽  
Eric L. Petersen ◽  
Alexander Heufer ◽  
Nicola Donohoe ◽  
Wayne Metcalfe ◽  
...  

Depending on the feedstock and the production method, the composition of syngas can include (in addition to H2 and CO) small hydrocarbons, diluents (CO2, water, and N2), and impurities (H2S, NH3, NOx, etc.). Despite this fact, most of the studies on syngas combustion do not include hydrocarbons or impurities and in some cases not even diluents in the fuel mixture composition. Hence, studies with realistic syngas composition are necessary to help designing gas turbines. The aim of this work was to investigate numerically the effect of the variation in the syngas composition on some fundamental combustion properties of premixed systems such as laminar flame speed and ignition delay time at realistic engine operating conditions. Several pressures, temperatures, and equivalence ratios were investigated. To perform this parametric study, a state-of-the-art C0-C5 detailed kinetics mechanism was used. Results of this study showed that the addition of hydrocarbons generally reduces the reactivity of the mixture (longer ignition delay time, slower flame speed) due to chemical kinetic effects. The amplitude of this effect is however dependent on the nature and concentration of the hydrocarbon as well as the initial condition (pressure, temperature, and equivalence ratio).


2017 ◽  
Vol 140 (1) ◽  
Author(s):  
Guangying Yu ◽  
Omid Askari ◽  
Hameed Metghalchi

A numerical study has been carried out to investigate the impact of adding syngas into JP-8 fuel. A new chemical mechanism has been assembled from existing mechanism of JP-8 and syngas and has been examined by comparing with the experimental data from literatures. The mechanism was then applied to Cantera zero-dimension constant internal energy and constant volume model and one-dimensional (1D) freely propagating flame model to calculate the ignition delay time and laminar burning speed, respectively. The simulations were carried out over a large range of temperature (700–1000 K), blending ratio (0–20% syngas), and H2/CO ratio (10/90 to 50/50). Simulation results showed that the blending syngas with JP-8 will slightly increase the ignition delay time and laminar burning speed.


Author(s):  
A. G. Korotkikh ◽  
◽  
V. A. Arkhipov ◽  
I. V. Sorokin ◽  
E. A. Selikhova ◽  
...  

The paper presents the results of ignition and thermal behavior for samples of high-energy materials (HEM) based on ammonium perchlorate (AP) and ammonium nitrate (AN), active binder and powders of Al, B, AlB2, and TiB2. A CO2 laser with a heat flux density range of 90-200 W/cm2 was used for studies of ignition. The activation energy and characteristics of ignition for the HEM samples were determined. Also, the ignition delay time and the surface temperature of the reaction layer during the heating and ignition for the HEM samples were determined. It was found that the complete replacement of micron-sized aluminum powder by amorphous boron in a HEM sample leads to a considerable decrease in the ignition delay time by a factor of 2.2-2.8 at the same heat flux density due to high chemical activity and the difference in the oxidation mechanisms of boron particles. The use of aluminum diboride in a HEM sample allows one to reduce the ignition delay time of a HEM sample by a factor of 1.7-2.2. The quasi-stationary ignition temperature is the same for the AlB2-based and AlB12-based HEM samples.


Author(s):  
Haoqiang Sheng ◽  
Xiaobin Huang ◽  
Zhijia Chen ◽  
Zhengchuang Zhao ◽  
Hong Liu

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