Phase behaviour and physico-chemical properties of the binary systems {1-ethyl-3-methylimidazolium thiocyanate, or 1-ethyl-3-methylimidazolium tosylate+water, or+an alcohol}

2010 ◽  
Vol 294 (1-2) ◽  
pp. 72-83 ◽  
Author(s):  
Urszula Domańska ◽  
Marta Królikowska ◽  
Marek Królikowski
1985 ◽  
Vol 50 (8) ◽  
pp. 1629-1635 ◽  
Author(s):  
Marie Šišková ◽  
Jiřina Hejtmánková ◽  
Lidmila Bartovská

Surface tension of two binary systems ammonium nitrate-water and urea-water and of the ternary system ammonium nitrate-urea-water was measured as a function of concentration at 20 and 40 °C. The experimental values were compared with those calculated from the relations which were proposed for calculating surface tensions of ternary systems from measured surface tensions of both binary systems.


2011 ◽  
Vol 303 (1) ◽  
pp. 1-9 ◽  
Author(s):  
Urszula Domańska ◽  
Marta Królikowska ◽  
Kamil Paduszyński

1983 ◽  
Vol 48 (4) ◽  
pp. 1097-1103
Author(s):  
Ludmila Bartovská ◽  
Jiřina Hejtmánková ◽  
Marie Šišková ◽  
Lubomír Jäger

Density of the ternary system urea-ammonium nitrate-water was measured in the range of overall concentrations 0-75 mass % at temperatures of 0, 20, 30 and 40 °C. The experimental data are compared with the values calculated from the relation obtained by combining the temperature dependences of densities of the binary systems urea-water and ammonium nitrate-water.


Author(s):  
H. Gross ◽  
H. Moor

Fracturing under ultrahigh vacuum (UHV, p ≤ 10-9 Torr) produces membrane fracture faces devoid of contamination. Such clean surfaces are a prerequisite foe studies of interactions between condensing molecules is possible and surface forces are unequally distributed, the condensate will accumulate at places with high binding forces; crystallites will arise which may be useful a probes for surface sites with specific physico-chemical properties. Specific “decoration” with crystallites can be achieved nby exposing membrane fracture faces to water vopour. A device was developed which enables the production of pure water vapour and the controlled variation of its partial pressure in an UHV freeze-fracture apparatus (Fig.1a). Under vaccum (≤ 10-3 Torr), small container filled with copper-sulfate-pentahydrate is heated with a heating coil, with the temperature controlled by means of a thermocouple. The water of hydration thereby released enters a storage vessel.


1990 ◽  
Vol 63 (03) ◽  
pp. 499-504 ◽  
Author(s):  
A Electricwala ◽  
L Irons ◽  
R Wait ◽  
R J G Carr ◽  
R J Ling ◽  
...  

SummaryPhysico-chemical properties of recombinant desulphatohirudin expressed in yeast (CIBA GEIGY code No. CGP 39393) were reinvestigated. As previously reported for natural hirudin, the recombinant molecule exhibited abnormal behaviour by gel filtration with an apparent molecular weight greater than that based on the primary structure. However, molecular weight estimation by SDS gel electrophoresis, FAB-mass spectrometry and Photon Correlation Spectroscopy were in agreement with the theoretical molecular weight, with little suggestion of dimer or aggregate formation. Circular dichroism studies of the recombinant molecule show similar spectra at different pH values but are markedly different from that reported by Konno et al. (13) for a natural hirudin-variant. Our CD studies indicate the presence of about 60% beta sheet and the absence of alpha helix in the secondary structure of recombinant hirudin, in agreement with the conformation determined by NMR studies (17)


1963 ◽  
Vol 79 (2) ◽  
pp. 263-293 ◽  
Author(s):  
E.M. Savitskii ◽  
V.F. Terekhova ◽  
O.P. Naumkin

1990 ◽  
Vol 39 (442) ◽  
pp. 996-1000 ◽  
Author(s):  
Ayao TAKASAKA ◽  
Hideyuki NEMOTO ◽  
Hirohiko KONO ◽  
Yoshihiro MATSUDA

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