In-situ diffraction techniques for studying hydrogen storage materials under high hydrogen pressure

2012 ◽  
Vol 37 (13) ◽  
pp. 10182-10195 ◽  
Author(s):  
E.MacA. Gray ◽  
C.J. Webb
2019 ◽  
Vol 3 (4) ◽  
pp. 956-964 ◽  
Author(s):  
Jun Sugiyama ◽  
Izumi Umegaki ◽  
Mitsuru Matsumoto ◽  
Kazutoshi Miwa ◽  
Hiroshi Nozaki ◽  
...  

To study the mechanism determining the desorption temperature of hydrogen storage materials, we have measured muon spin rotation and relaxation (μ+SR) in MgH2 together with the pressure in the sample space.


2012 ◽  
Vol 45 (5) ◽  
pp. 902-905 ◽  
Author(s):  
Roxana Flacau ◽  
Jim Bolduc ◽  
Thomas Bibienne ◽  
Jacques Huot ◽  
Helmut Fritzsche

In situneutron powder diffraction (NPD) measurements of hydrogenation processes taking place at high temperatures pose difficulties related to the choice of sample can material. This article describes a simple design for a copper-coated vanadium can and its connection to the gas-handling system, tested up to 523 K. High-quality NPD patterns of TiV1.2Mn0.8body-centred cubic alloy, as-cast and partially hydrogenated, were collected at 373 K and deuterium pressures up to 2 bar (200 kPa).


RSC Advances ◽  
2019 ◽  
Vol 9 (1) ◽  
pp. 408-428 ◽  
Author(s):  
Jianfeng Zhang ◽  
Zhinian Li ◽  
Yuanfang Wu ◽  
Xiumei Guo ◽  
Jianhua Ye ◽  
...  

Magnesium hydride and its compounds have a high hydrogen storage capacity and are inexpensive, and thus have been considered as one of the most promising hydrogen storage materials for on-board applications.


2011 ◽  
Vol 236-238 ◽  
pp. 668-671
Author(s):  
Shi Gang Kang ◽  
Zhi Min Zong ◽  
Heng Fu Shui ◽  
Zhi Cai Wang ◽  
Xian Yong Wei

The hydrogenation of preasphaltene (PA), from Chinese Xiaolongtan lignite liquefied heavy product, was investigated with hydrogen storage materials in a batch autoclave. The effects of reaction conditions such as hydrogen storage materials and temperature on the yields of gas+oil, asphaltene, char and the conversions of preasphaltene were discussed. Preliminary studies indicate that increasing temperature not only improves hydrogen donor performance of hydrogen storage materials but also enhances conversion of feedstock PA and gas+oil yield. The conversion of PA and the yield gas+oil get to 72.02% and 41.46%, respectively, under 5% MgH2, 5MPa initial hydrogen pressure, temperature 420°C and reaction time 30min. Meanwhile MgH2 is stronger than NaBH4 in hydrodeoxygenation of PA under the same conditions. Elemental and FTIR analyses were used to illustrate the structural characteristics of feedstock PA and remaining preasphaltene (RPA).


2015 ◽  
Vol 3 (16) ◽  
pp. 8294-8299 ◽  
Author(s):  
Yi Jia ◽  
Chenghua Sun ◽  
Ye Peng ◽  
Wenqi Fang ◽  
Xuecheng Yan ◽  
...  

The facile and scalable fabrication of ultrafine (<5 nm) nanoparticles (NPs) as effective catalysts is the key for enhancing the kinetics of most hydrogen storage materials (HSMs).


1995 ◽  
Vol 33 (2-3) ◽  
pp. 53-57 ◽  
Author(s):  
Ming Au ◽  
F. Pourarian ◽  
S.G. Sankar ◽  
W.E. Wallace ◽  
Lian Zhang

Materia Japan ◽  
2009 ◽  
Vol 48 (12) ◽  
pp. 616-616
Author(s):  
Shigehito Isobe ◽  
Yongming Wang ◽  
Koya Okudera ◽  
Hiroko Hirasawa ◽  
Naoyuki Hashimoto ◽  
...  

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