Synthesis of lanthanum – cerium - terbium condensed phosphates and their fluorescence properties for redox environments

Optik ◽  
2020 ◽  
Vol 207 ◽  
pp. 163770
Author(s):  
Hiroaki Onoda ◽  
Kengo Ikeuchi
1967 ◽  
Vol 64 ◽  
pp. 173-182 ◽  
Author(s):  
Erhard J. Schimitschek ◽  
Richard B. Nehrich Jr ◽  
John A. Trias

2000 ◽  
Vol 72 (3) ◽  
pp. 415 ◽  
Author(s):  
Joydip Das ◽  
Rosalie K. Crouch ◽  
Parkson Lee-Gau Chong

1965 ◽  
Vol 29 (4) ◽  
pp. 487-488
Author(s):  
R. R. Allmaras ◽  
C. A. Black

1992 ◽  
Vol 57 (12) ◽  
pp. 2475-2480 ◽  
Author(s):  
Milan Brutovský ◽  
Štefan Gerej ◽  
Ján Novák ◽  
Lucia Ferdinandyová

Catalysts were prepared from VOPO4.xH2O.yH3PO4 (x = 0.3-2, y = 0.2-0.85) by reduction with SO2 up to a final temperature of 750-800 °C, and activated in a reaction mixture of 1.0-1.4% butane in air up to 500 °C. The structure characteristics and phase composition of the catalysts were found to be affected by the preparation procedure and heat treatment regime. Their diffraction lines and IR spectra revealed that the catalysts from larger and less defective crystals than catalysts which were obtained from the VOHPO4.xH2O.yH3PO4 precursor and activated in the reaction mixture at temperatures up to 500 °C. In the catalysts prepared by the above procedure, the tendency to the formation of phases of higher-condensed phosphates, in particular VO(PO3)2 or even V(PO3)3, increases with increasing n(P):n(V) ratio and is then more pronounced than with vanadium-phosphorus catalysts prepared by other procedures. The tendency to the formation of the catalytically less active condensed phosphates is partly suppressed by the embedding of modifying metal cations (Fe or Cu in this case).


Author(s):  
Keita Nobuhara ◽  
Yusuke Inagaki ◽  
Wataru Setaka

Intramolecular charge transfer (ICT) fluorescence has been widely investigated and exploited in sensor molecules. However, steric effects on the ICT fluorescence properties have rarely been reported so far, although research...


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