Low-cost CuNi-CeO2/rGO as an efficient catalyst for hydrolysis of ammonia borane and tandem reduction of 4-nitrophenol

2017 ◽  
Vol 728 ◽  
pp. 902-909 ◽  
Author(s):  
Ying-Hua Zhou ◽  
Suqin Wang ◽  
Yu Wan ◽  
Jingjing Liang ◽  
Yu Chen ◽  
...  
2018 ◽  
Vol 43 (5) ◽  
pp. 2754-2762 ◽  
Author(s):  
Yang Liu ◽  
Huijuan Guan ◽  
Jun Zhang ◽  
Yafei Zhao ◽  
Jing-He Yang ◽  
...  

RSC Advances ◽  
2018 ◽  
Vol 8 (22) ◽  
pp. 12282-12291 ◽  
Author(s):  
Shuren Zhang ◽  
Liqun Zhou ◽  
Menghuan Chen

The performance of Ru-based catalyst for hydrolysis of AB can be significantly enhanced through amine-functionalization of the MOF material.


Nanomaterials ◽  
2019 ◽  
Vol 9 (9) ◽  
pp. 1334 ◽  
Author(s):  
Yufa Feng ◽  
Jin Zhang ◽  
Huilong Ye ◽  
Liling Li ◽  
Huize Wang ◽  
...  

The catalytic hydrolysis of ammonia borane (AB) is a promising route to produce hydrogen for mobile hydrogen‒oxygen fuel cells. In this study, we have successfully synthesized a variety of Ni0.5Cu0.5Co2O4 nanocomposites with different morphology, including nanoplatelets, nanoparticles, and urchin-like microspheres. The catalytic performance of those Ni0.5Cu0.5Co2O4 composites in AB hydrolysis is investigated. The Ni0.5Cu0.5Co2O4 nanoplatelets show the best catalytic performance despite having the smallest specific surface area, with a turnover frequency (TOF) of 80.2 molhydrogen·min−1·mol−1cat. The results reveal that, in contrast to the Ni0.5Cu0.5Co2O4 nanoparticles and microspheres, the Ni0.5Cu0.5Co2O4 nanoplatelets are more readily reduced, leading to the fast formation of active species for AB hydrolysis. These findings provide some insight into the design of high-performance oxide-based catalysts for AB hydrolysis. Considering their low cost and high catalytic activity, Ni0.5Cu0.5Co2O4 nanoplatelets are a strong candidate catalyst for the production of hydrogen through AB hydrolysis in practical applications.


2019 ◽  
Vol 6 (5) ◽  
pp. 1189-1194 ◽  
Author(s):  
Jingang Yang ◽  
Qi Yuan ◽  
Yuan Liu ◽  
Xianglong Huang ◽  
Yanxiu Qiao ◽  
...  

A Ni–Fe–P layer coating on Ni foam is composed of connected irregular patches and shows prominent cost-performance for hydrolysis of AB.


2016 ◽  
Vol 4 (22) ◽  
pp. 8579-8583 ◽  
Author(s):  
Qilu Yao ◽  
Zhang-Hui Lu ◽  
Wei Huang ◽  
Xiangshu Chen ◽  
Jia Zhu

Ni nanocatalysts modified with a Mo dopant and a graphene support have been used as a low cost catalyst with Pt-like activity and robust durability for hydrogen evolution from the hydrolysis of ammonia borane under ambient atmosphere at room temperature.


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