Ruthenium nanoparticles loaded on multiwalled carbon nanotubes for liquid-phase hydrogenation of fine chemicals: An exploration of confinement effect

2015 ◽  
Vol 329 ◽  
pp. 95-106 ◽  
Author(s):  
Yong Wang ◽  
Zeming Rong ◽  
Yu Wang ◽  
Peng Zhang ◽  
Yue Wang ◽  
...  
2020 ◽  
Vol 7 (21) ◽  
pp. 2002225
Author(s):  
Yuchi Fan ◽  
Erhong Song ◽  
Tufail Mustafa ◽  
Ruicong Liu ◽  
Pengpeng Qiu ◽  
...  

2005 ◽  
Vol 899 ◽  
Author(s):  
Mohit Kumar ◽  
Naveen Rawat ◽  
Kalathur S Santhanam

AbstractThe effect of nanostructure on the thermal oxidation of atomized iron has been investigated. Above 500°C atomized iron is oxidized in the presence of air. However, when iron is compacted with multiwalled carbon nanotubes (MWCNT) this oxidation is shifted by more than 100°C. Iron is protected by the nanostructure environment A large number of compositions of atomic ratios of iron and MWCNT have been examined in this study to understand the effect in detail. The effect of nanostructure in the thermal oxidation of iron is interpreted as due to iron atom experiencing extensive overlap and confinement effect. causing spin transfer. Based on theoretical calculations reported in the literature this confinement effect of iron is suggested to produce a transformation from 3d64s2 to an effective configuration of 3d84s0 producing spintronics effect.


2008 ◽  
Vol 8 (4) ◽  
pp. 2044-2048 ◽  
Author(s):  
Naveen Rawat ◽  
Russel Gudyaka ◽  
Mohit Kumar ◽  
Bharat Joshi ◽  
Kalathur S. V. Santhanam

This paper describes the thermal oxidative behavior of atomized iron or atomized cobalt in the presence of multiwalled carbon nanotubes (MWCNT). The thermogravimetric analysis shows the atomized iron thermal oxidation starts at about 500 °C that is absent when the atomized iron is sintered with multiwalled carbon naonotubes. The thermal oxidation of iron in the sintered samples requires the collapse of the multiwalled carbon nanotubes. A similar behavior is observed with atomized cobalt when its oxidation requires the collapse of the nanotubes. This thermal oxidative shift is interpreted as due to the atomized iron or atomized cobalt atom experiencing extensive overlap and confinement effect with multiwalled carbon nanotubes causing a spin transfer. This confinement effect is suggested to produce a transformation of iron from the outermost electronic distribution of 3d64s2 to an effective configuration of 3d84s0 and for cobalt 3d74s2 to 3d94s0 producing spintronics effect.


2012 ◽  
Vol 2 (6) ◽  
pp. 166-168 ◽  
Author(s):  
Dr.T.Ch.Madhavi Dr.T.Ch.Madhavi ◽  
◽  
Pavithra.P Pavithra.P ◽  
Sushmita Baban Singh Sushmita Baban Singh ◽  
S.B.Vamsi Raj S.B.Vamsi Raj ◽  
...  

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