Leaching behavior of zinc and lead from electric arc furnace dust – Poly(vinyl) chloride residues after oxidative thermal treatment

2021 ◽  
pp. 129622
Author(s):  
Mohammad Al-Harahsheh ◽  
Sanad Altarawneh ◽  
Mohammad Al-Omari ◽  
Mohammednoor Altarawneh ◽  
Sam Kingman ◽  
...  
2015 ◽  
Vol 41 (4) ◽  
pp. 62-66 ◽  
Author(s):  
Ahmet Can Bayraktar ◽  
Edip Avşar ◽  
İsmail Toröz ◽  
Kadir Alp ◽  
Asude Hanedar

Abstract In this study, solidification/stabilization (S/S) of electric arc furnace dust (EAFD) which is generated during the production of steel from scrap metals and classified as hazardous waste were investigated by using different ratios of cement and low grade MgO (LG MgO) as binding agents. Type I PC 42.5 R portland cement and LG MgO which contains 70–80% MgO were used. S/S blocks that contain different ratios of binding agents which have 1/0.5 – 1/1 – 1/2 – 1/3 – 1/4 – 1/5 cement/LG MgO ratio and S/S blocks which contain only cement and no LG MgO agents were prepared. These blocks, which contain 3 different waste ratios according to weight, 20%, 30% and 40% respectively, were produced and exposed to 28-day water purification. At the end of the purification process, S/S blocks were extracted using TCLP (Toxicity Characteristic Leaching Procedure) tests in order to determine the leaching behavior of Zn, Pb, and Cd in S/S blocks. By the end of this study, it was concluded that the recovery of EAFD is possible and applicable by immobilization. The findings of the study concluded that environmental performances or structural properties of blocks contain 30% waste by weight are suitable. This method is a proper one for recovering and treatment of EAFD with mixture of cement and LG MgO.


Author(s):  
Galal Fares ◽  
Abdulaziz I. Al-Negheimish ◽  
Fahad M. Al-Mutlaq ◽  
Abdulrahman M. Alhozaimy ◽  
M. Iqbal Khan

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Ayman Galal ◽  
Olfat Sadek ◽  
Moataz Soliman ◽  
Shaker Ebrahim ◽  
M. Anas

AbstractElectric arc furnace dust (EAFD) and waste pickle liquor (WPL); two major side products of the steel industry with negative environmental impact were used for the synthesis of nickel zinc ferrite (NZF); the important magnetic ceramic material of versatile industrial applications. The structural and magnetic properties of the prepared material were examined which showed good magnetic properties (high saturation magnetization and low coercivity) compared with those synthesized from pure reagents. In the applied process, nano sized nickel zinc ferrite (NZF) with a composition of Nix(Zn + impurities)1−xFe2O4 (where x = 0, 0.25, 0.5, 0.75 and impurities of manganese, magnesium, and calcium were prepared using zinc-containing electric arc furnace dust (EAFD) and waste pickle liquor (WPL). The chemical compositions of the prepared samples were determined using X-ray fluorescence (XRF) analysis. The optimum acetic acid concentration for EAFD treatment was found 2% v/v that decreased Ca content of EAFD by 70.6% without loss of Fe and Zn. The structural and morphological characterization was done by X-ray diffraction (XRD), Fourier transform infrared (FTIR) and Field Emission Scanning Electron Microscope (FESEM) to confirm the formation of Ni–Zn ferrite nanoparticles and estimate the particle sizes. The maximum saturation magnetization (Ms) of 73.89 emu/g was achieved at 0.5 Ni content and the minimum coercivity of 2.55 Oe was obtained at 0.25 Ni content.


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