Effect of metal salts impregnation and microwave-assisted solvent pretreatment on selectivity of levoglucosenone and levoglucosan from vacuum pyrolysis of ashe juniper waste

2019 ◽  
Vol 7 (1) ◽  
pp. 102796 ◽  
Author(s):  
Julius Choi ◽  
Hyungseok Nam ◽  
Sergio C. Capareda
RSC Advances ◽  
2014 ◽  
Vol 4 (27) ◽  
pp. 14149-14156 ◽  
Author(s):  
Michael T. Kessler ◽  
Maria K. Hentschel ◽  
Christina Heinrichs ◽  
Stefan Roitsch ◽  
Martin H. G. Prechtl

Herein we present a general approach to metal and metal oxide nanoparticles using simple metal salts as starting materials.


2021 ◽  
Vol 07 ◽  
Author(s):  
Fumiyoshi Ozaki ◽  
Yutaka Okada

: Microwave-assisted Claisen rearrangement of allyloxybenzene with a hydroxyl group was conducted in the presence of metal salts. The rearrangement was promoted in the presence of an alkali metal salt, because the reaction substrate was converted to a phenoxide-type ion, which can efficiently absorb microwaves. In contrast, a Lewis acid was strongly coordinated to the ethereal oxygen, and this structure could also absorb microwaves efficiently.


2010 ◽  
Vol 65 (2) ◽  
pp. 168-172 ◽  
Author(s):  
Baohui Zheng ◽  
Zhijie Fang ◽  
Jie Cheng ◽  
Yuhua Jiang

A convenient system for producing 5-hydroxymethylfurfural (HMF) through dehydration of carbohydrates by microwave heating in the presence of ZnCl2 was studied. The use of ZnCl2 gave higher selectivity than other metal salts in the conversion of glucose. With ZnCl2 as catalyst, sucrose could be utilized effectively. Under the conditions of microwave irradiation (300 W, 8 min), HMF yields were 54.6, 55.1, and 80.6% from glucose, fructose and sucrose, whereas upon conventional oil bath heating (0.11 gmL−1 sugar solution, weight ratio of ZnCl2 to substrate = 1 : 4, 189 °C, 60 min) HMF yields from glucose, fructose and sucrose were only up to 37.7, 42.7, and 57.7%, respectively.


Author(s):  
Debadyoti Ghosh ◽  
G S Taki ◽  
Ayush Bhattacharya ◽  
Anusha Chatterjee ◽  
Himeli Pandit

2016 ◽  
Vol 18 (6) ◽  
pp. 1516-1523 ◽  
Author(s):  
Yao-Bing Huang ◽  
Tao Yang ◽  
Meng-Chao Zhou ◽  
Hui Pan ◽  
Yao Fu

The alcoholysis of furfuryl alcohol with different alcohols was carried out by using metal salt catalysts under microwave conditions, achieving high alkyl levulinates’ yields in a short reaction time.


2014 ◽  
Vol 2014 ◽  
pp. 1-5 ◽  
Author(s):  
Ali Maleki ◽  
Ali Hossein Rezayan

A one-pot microwave-assisted synthesis of metallopyrazinoporphyrazines as porphyrazine derivatives carrying six-membered pyrazine rings annulated at the periphery of the tetrapyrrolic macrocycle is described starting from 2,3-diaminomaleonitrile, 1,2-dicarbonyl compounds, metal salts, and urea.


RSC Advances ◽  
2017 ◽  
Vol 7 (73) ◽  
pp. 46520-46528 ◽  
Author(s):  
Fu-hua Wei ◽  
Ding Chen ◽  
Zhao Liang ◽  
Shuai-qi Zhao ◽  
Yun Luo

In this study, four metal–organic frameworks (MOFs) were prepared using a simple, low-cost, and high-efficiency technique utilizing simple carboxylic acids and metal salts by microwave-assisted ball milling.


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