Electrochemical activation and renewal of pyrrole nitrogen sites in porphyrin-based conjugated polymer for simultaneous determination of uric acid and adrenaline

2021 ◽  
Vol 884 ◽  
pp. 115055
Author(s):  
Xiaoya Liu ◽  
Hepeng Ji ◽  
Junyan Tang ◽  
Feifei Tao ◽  
Xicheng Zhang ◽  
...  
2014 ◽  
Vol 2014 ◽  
pp. 1-10 ◽  
Author(s):  
Gen Liu ◽  
Wei Ma ◽  
Yan Luo ◽  
Deng-ming Sun ◽  
Shuang Shao

Poly(methylene blue) and electrochemically reduced graphene oxide composite film modified electrode (PMB-ERGO/GCE) was successfully fabricated by electropolymerization and was used for simultaneous determination of uric acid (UA) and xanthine (Xa). Based on the excellent electrocatalytic activity of PMB-ERGO/GCE, the electrochemical behaviors of UA and Xa were studied by cyclic voltammetry (CV) and square wave voltammetry (SWV). Two anodic sensitive peaks at 0.630 V (versus Ag/AgCl) for UA and 1.006 V (versus Ag/AgCl) for Xa were given by CV in pH 3.0 phosphate buffer. The calibration curves for UA and Xa were obtained in the range of 8.00 × 10−8~4.00 × 10−4 M and 1.00 × 10−7~4.00 × 10−4 M, respectively, by SWV. The detection limits for UA and Xa were3.00×10-8 M and5.00×10-8 M, respectively. Finally, the proposed method was applied to simultaneously determine UA and Xa in human urine with good selectivity and high sensitivity.


2017 ◽  
Vol 799 ◽  
pp. 459-467 ◽  
Author(s):  
Qing Zhu ◽  
Jing Bao ◽  
Danqun Huo ◽  
Mei Yang ◽  
Huixiang Wu ◽  
...  

Lab on a Chip ◽  
2011 ◽  
Vol 11 (7) ◽  
pp. 1286 ◽  
Author(s):  
Jinghua Yu ◽  
Lei Ge ◽  
Jiadong Huang ◽  
Shoumei Wang ◽  
Shenguang Ge

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