Degradation of natural organic matter in surface water using vacuum-UV irradiation

2011 ◽  
Vol 186 (1) ◽  
pp. 240-246 ◽  
Author(s):  
Gustavo Imoberdorf ◽  
Madjid Mohseni
Keyword(s):  
Organic Matter ◽  
Surface Water ◽  
Natural Organic Matter ◽  
Uv Irradiation ◽  
Vacuum Uv

scholarly journals Degradation and transformation of natural organic matter accountable for disinfection byproduct formations by UV photolysis and UV/chlor(am)ine

2018 ◽  
Vol 79 (5) ◽  
pp. 929-937 ◽  
Author(s):  
Chanathip Hirun-Utok ◽  
Songkeart Phattarapattamawong
Keyword(s):  
Organic Matter ◽  
Natural Organic Matter ◽  
Low Pressure ◽  
Haloacetic Acid ◽  
Uv Photolysis ◽  
Disinfection Byproduct ◽  
Proportional Relationship ◽  
Vacuum Uv ◽  
Potential Use

Abstract This research aimed to investigate the degradation of natural organic matter responsible for the formation of trihalomethane (THM), haloacetic acid (HAA) and haloacetonitrile (HAN) during ultraviolet (UV) photolysis and a co-exposure of UV with chlorine (UV/chlorine) and chloramine (UV/chloramine). Low pressure UV (LPUV) and vacuum UV (VUV) lamps were used for photolysis. VUV and LPUV irradiation changed aromatic/unsaturated structures to aliphatic ones, resulting in decreased THM and HAN formation. Following irradiation for 60 min, LPUV decreased THM and HAN by 16% ± 2% and 20% ± 6%, respectively. VUV decreased THM and HAN formation by 23% ± 3% and 20% ± 8%, respectively. HAA formation increased following photolysis. UV/chlorine treatment decreased THM, HAA and HAN. Higher chlorine doses had an inversely proportional relationship with THM and HAN formation. A chlorine dose of 4 mg·L−1 led to the greatest reductions, corresponding to 42% ± 2%, 10% ± 10% and 18% ± 6% for THM, HAA and HAN, respectively. UV/chloramine decreased the formation of THM more than UV/chlorine. With a chloramine dose of 4 mg·L−1, THM, HAA and HAN formation decreased by 74% ± 10%, 10% ± 10% and 11% ± 10%, respectively. This study showed the potential use of UV/chlor(am)ine for controlling the formation of THM, HAA and HAN.

Application of composite flocculants for removing organic matter and mitigating ultrafiltration membrane fouling in surface water treatment: the role of composite ratio

2019 ◽  
Vol 5 (12) ◽  
pp. 2242-2250
Author(s):  
Xue Shen ◽  
Baoyu Gao ◽  
Kangying Guo ◽  
Qinyan Yue
Keyword(s):  
Organic Matter ◽  
Water Treatment ◽  
Surface Water ◽  
Membrane Permeability ◽  
Natural Organic Matter ◽  
Membrane Fouling ◽  
Ultrafiltration Membrane ◽  
Surface Water Treatment ◽  
Ultrafiltration Membrane Fouling

Coagulation prior to the ultrafiltration (UF) process was implemented to improve natural organic matter (NOM) removal and membrane permeability.

Comparison of disinfection byproduct (DBP) formation from different UV technologies at bench scale

2002 ◽  
Vol 2 (5-6) ◽  
pp. 515-521 ◽  
Author(s):  
W. Liu ◽  
S.A. Andrews ◽  
J.R. Bolton ◽  
K.G. Linden ◽  
C. Sharpless ◽  
...  
Keyword(s):  
Organic Matter ◽  
Carboxylic Acids ◽  
Natural Organic Matter ◽  
Uv Irradiation ◽  
Direct Action ◽  
Disinfection Byproduct ◽  
Pressure Medium ◽  
The Impact ◽  
As Effects

The impact of UV irradiation on disinfection byproduct (DBP) formation was investigated for low pressure, medium pressure and pulsed UV technologies using a broad range of UV doses. Four classes of DBPs (THMs, HAAs, aldehydes and carboxylic acids) were examined. This enabled the determination of effects resulting from the direct action of UV irradiation on natural organic matter (aldehydes, carboxylic acids) as well as effects on the ultimate formation of chlorinated DBPs (THMs and HAAs) from secondary chlorination. For doses of less than 1,000 mJ/cm2, UV irradiation did not affect THM and HAA formation in subsequent chlorination processes, however higher UV doses resulted in lower ultimate concentrations of THMs and HAAs. UV irradiation also resulted in the formation of aldehydes and carboxylic acids at UV doses above 500 mJ/cm2, compounds that are known to adversely effect drinking water biostability.

scholarly journals Impacts of Natural Organic Matter Adhesion on Irreversible Membrane Fouling during Surface Water Treatment Using Ultrafiltration

Membranes ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 238
Author(s):  
Fangshu Qu ◽  
Zhimeng Yang ◽  
Shanshan Gao ◽  
Huarong Yu ◽  
Junguo He ◽  
...  
Keyword(s):  
Organic Matter ◽  
Surface Water ◽  
Natural Organic Matter ◽  
Membrane Fouling ◽  
Adhesion Forces ◽  
Cake Filtration ◽  
Force Microscopy ◽  
Surface Water Treatment ◽  
Atomic Force ◽  
Colloidal Probes

To understand impacts of organic adhesion on membrane fouling, ultrafiltration (UF) membrane fouling by dissolved natural organic matter (NOM) was investigated in the presence of background cations (Na+ and Ca2+) at typical concentrations in surface water. Moreover, NOM adhesion on the UF membrane was investigated using atomic force microscopy (AFM) with colloidal probes and a quartz crystal microbalance with dissipation monitoring (QCM-D). The results indicated that the adhesion forces at the NOM-membrane interface increased in the presence of background cations, particularly Ca2+, and that the amount of adhered NOM increased due to reduced electrostatic repulsion. However, the membrane permeability was almost not affected by background cations in the pore blocking-dominated phase but was aggravated to some extent in the cake filtration-governed phase. More importantly, the irreversible NOM fouling was not correlated with the amount of adhered NOM. The assumption for membrane autopsies is doubtful that retained or adsorbed organic materials are necessarily a primary cause of membrane fouling, particularly the irreversible fouling.

TiO2Photocatalysis of Natural Organic Matter in Surface Water: Impact on Trihalomethane and Haloacetic Acid Formation Potential

2008 ◽  
Vol 42 (16) ◽  
pp. 6218-6223 ◽  
Author(s):  
Sanly Liu ◽  
May Lim ◽  
Rolando Fabris ◽  
Christopher Chow ◽  
Mary Drikas ◽  
...  
Keyword(s):  
Organic Matter ◽  
Surface Water ◽  
Natural Organic Matter ◽  
Acid Formation ◽  
Water Impact ◽  
Haloacetic Acid ◽  
Formation Potential

A comparison of surface water natural organic matter in raw filtered water samples, XAD, and reverse osmosis isolates

2002 ◽  
Vol 36 (9) ◽  
pp. 2357-2371 ◽  
Author(s):  
Patricia A. Maurice ◽  
Michael J. Pullin ◽  
Stephen E. Cabaniss ◽  
Qunhui Zhou ◽  
Ksenija Namjesnik-Dejanovic ◽  
...  
Keyword(s):  
Organic Matter ◽  
Surface Water ◽  
Reverse Osmosis ◽  
Natural Organic Matter ◽  
Water Samples

Fate of effluent organic matter (EfOM) and natural organic matter (NOM) through riverbank filtration

2008 ◽  
Vol 57 (12) ◽  
pp. 1999-2007 ◽  
Author(s):  
S. K. Maeng ◽  
S. K. Sharma ◽  
A. Magic-Knezev ◽  
G. Amy
Keyword(s):  
Organic Matter ◽  
Surface Water ◽  
Natural Organic Matter ◽  
Wastewater Effluent ◽  
Riverbank Filtration ◽  
Soil Columns ◽  
Effluent Organic Matter ◽  
Bulk Organic Matter ◽  
Water And Wastewater ◽  
The Impact

Understanding the fate of effluent organic matter (EfOM) and natural organic matter (NOM) through riverbank filtration is essential to assess the impact of wastewater effluent on the post treatment requirements of riverbank filtrates. Furthermore, their fate during drinking water treatment can significantly determine the process design. The objective of this study was to characterise bulk organic matter which consists of EfOM and NOM during riverbank filtration using a suite of innovative analytical tools. Wastewater effluent-derived surface water and surface water were used as source waters in experiments with soil columns. Results showed the preferential removal of non-humic substances (i.e. biopolymers) from wastewater effluent-derived surface water. The bulk organic matter characteristics of wastewater effluent-derived surface water and surface water were similar after 5 m soil passage in laboratory column experiment. Humic-like organic matter in surface water and wastewater effluent-derived surface water persisted through the soil passage. More than 50% of total dissolved organic carbon (DOC) removal with significant reduction of dissolved oxygen (DO) was observed in the top 50 cm of the soil columns for both surface water and wastewater effluent-derived surface water. This was due to biodegradation by soil biomass which was determined by adenosine triphosphate (ATP) concentrations and heterotrophic plate counts. High concentrations of ATP in the first few centimeters of infiltration surface reflect the highest microbial activity which correlates with the extent of DOC reduction. Good correlation of DOC removal with DO and biomass development was observed in the soil columns.

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