Identification of commercial and recreational vessels coated with banned organotin paint through screening of tin by portable XRF

2019 ◽  
Vol 362 ◽  
pp. 107-114 ◽  
Author(s):  
Maria Lagerström ◽  
Daniel Yngsell ◽  
Britta Eklund ◽  
Erik Ytreberg
2019 ◽  
Author(s):  
Stephanie Tassier-Surine ◽  
◽  
Phillip J. Kerr ◽  
Kathleen R. Goff ◽  
Nick Lefler

Minerals ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 33
Author(s):  
Valérie Laperche ◽  
Bruno Lemière

Portable X-ray fluorescence spectroscopy is now widely used in almost any field of geoscience. Handheld XRF analysers are easy to use, and results are available in almost real time anywhere. However, the results do not always match laboratory analyses, and this may deter users. Rather than analytical issues, the bias often results from sample preparation differences. Instrument setup and analysis conditions need to be fully understood to avoid reporting erroneous results. The technique’s limitations must be kept in mind. We describe a number of issues and potential pitfalls observed from our experience and described in the literature. This includes the analytical mode and parameters; protective films; sample geometry and density, especially for light elements; analytical interferences between elements; physical effects of the matrix and sample condition, and more. Nevertheless, portable X-ray fluorescence spectroscopy (pXRF) results gathered with sufficient care by experienced users are both precise and reliable, if not fully accurate, and they can constitute robust data sets. Rather than being a substitute for laboratory analyses, pXRF measurements are a valuable complement to those. pXRF improves the quality and relevance of laboratory data sets.


2014 ◽  
Vol 143 ◽  
pp. 74-83 ◽  
Author(s):  
Michael F. Gazley ◽  
Chelsea M. Tutt ◽  
Louise A. Fisher ◽  
Aaron R. Latham ◽  
Guillaume Duclaux ◽  
...  

2005 ◽  
Vol 15 (01n02) ◽  
pp. 19-25 ◽  
Author(s):  
TETSUYA KOYAMA ◽  
JUN KAWAI

Applications of X-ray fluorescence (XRF) analysis to solid and liquid samples with a pyroelectric X-ray generator are described. The X-ray generator is driven by a 9 V dry electric battery and small dimensions. It enables compact and portable XRF spectrometer. It has disadvantages in low power and periodically changing X-ray flux. Measured solid samples are briquettes from powdery oxides of Ti , V , Cr , Mn , Fe , Co , Ni and Cu , and sulfide of Zn . Each sample is prepared to contain equal molar metal elements. Liquid samples are solutions of Fe , Cr , Zn , Pb , Bi , Cd . K α and K β lines of all metals in solid samples are detected. Although background level was relatively high for liquids, all metals in the measured samples were detected within 70 seconds, except for Cd . The capability of XRF with the pyroelectric X-ray generator is discussed.


1968 ◽  
Vol 5 (01) ◽  
pp. 63-71
Author(s):  
Philip J. Danahy

The paper presents a method for the determination of the critical minimum scantlings for small high-speed vessels. Particular attention is given to the shell plating strength for hydrodynamic impact loads. The suggested method uses an integrated approach involving assumed loads, suggested safety factors, and preferred stress-analysis method. The stress analysis uses plastic theory based partly on the works of J. Clarkson and Thein Wah. Included in the paper is a comparison of the relative structural strength of several commercial, military, and experimental hydrofoil vessels along with a few planing boats and a seaplane hull. This shows the variation of existing vessel structures and compares them to the results obtained by the suggested method. Most commercial, military, and recreational vessels exceed the minimum scantlings of the suggested method. The most significant deviation is the hull of the seaplane:


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