Corrosion protection of waterborne epoxy coatings containing mussel-inspired adhesive polymers based on polyaspartamide derivatives on carbon steel

2018 ◽  
Vol 34 (12) ◽  
pp. 2464-2471 ◽  
Author(s):  
Mingliang Yang ◽  
Jianhua Wu ◽  
Daqing Fang ◽  
Bo Li ◽  
Yang Yang
2018 ◽  
Vol 56 (3B) ◽  
pp. 96
Author(s):  
Anh Son Nguyen ◽  
Thuy Duong Nguyen ◽  
Thu Thuy Thai

The presence work investigates the corrosion protection of waterborne epoxy coatings containing CeO2 nanoparticles activated with cerium salt for the carbon steel substrates. First, the dispersion of activated nanoparticles in the epoxy matrix was observed by field emission scanning electron microscopy (FESEM). The electrochemical impedance spectroscopy (EIS) was carried out to evaluate the role of the activated-CeO2 nanoparticles in the organic coatings immersed in a 0.5 M NaCl solution. Thus, the effect of the cerium ion activated ceria nanoparticles on the coatings presented the artificial defect in the aggressive environment was examined via salt spray test. Complementary studies were performed using the cross-cut and pull-off test to assess the adherence properties of the samples. Results revealed that the presence of activated-CeO2 nanoparticles enhanced corrosion protection properties of waterborne epoxy coating without losing adherence properties.


2021 ◽  
Vol 159 ◽  
pp. 106394
Author(s):  
Zhenglin Tao ◽  
Jincan Cui ◽  
Hanxun Qiu ◽  
Junhe Yang ◽  
Shanglin Gao ◽  
...  

2017 ◽  
Vol 407 ◽  
pp. 213-222 ◽  
Author(s):  
Shihui Qiu ◽  
Cheng Chen ◽  
Mingjun Cui ◽  
Wei Li ◽  
Haichao Zhao ◽  
...  

2017 ◽  
Vol 419 ◽  
pp. 826-837 ◽  
Author(s):  
Yongsheng Hao ◽  
Luqman Abdullahi Sani ◽  
Tiejun Ge ◽  
Qinghong Fang

Polymers ◽  
2019 ◽  
Vol 11 (12) ◽  
pp. 1998 ◽  
Author(s):  
Yang Ding ◽  
Jiang Zhong ◽  
Ping Xie ◽  
Jinchuang Rong ◽  
Huifang Zhu ◽  
...  

Polypyrrole nanowires/graphene (PPyNG) nanocomposites as anticorrosive fillers were prepared by in situ polymerization in order to improve the anticorrosion performance of waterborne epoxy coatings. Field emission scanning electron microscope (FESEM) and Fourier transform infrared spectroscopy (FTIR) characterized the morphologies and structures of the synthesized PPyNG. The polypyrrole nanowires with about 50 nm in diameter were obtained. Conjugation length of PPy was increased with the addition of graphene. Open circuit potential (OCP) measurements, Tafel polarization curves, and electrochemical impedance spectroscopy (EIS) using an electrochemical workstation evaluated the anticorrosion properties of the waterborne epoxy/PPyNG coatings (EPPyNG). The studied nanocomposite coating possessed superior corrosion protection performance when the graphene content of the filler was 2 wt %. Its corrosion rate was about 100 times lower than that of neat epoxy coating. The higher barrier properties of nanocomposite coating and passivation effect of polypyrrole nanowires were beneficial in corrosion protection.


CORROSION ◽  
10.5006/3814 ◽  
2021 ◽  
Author(s):  
Fengjuan Xiao ◽  
Cheng Qian ◽  
Meng Wang ◽  
Xuefei Zhang ◽  
yan lu

Polyaniline nanofiber (PANI-f) was covalently linked with cetyltrimethyl ammonium bromide (CTAB) modified graphene oxide nanosheets (CTGO) to fabricate a smart composite coating for corrosion protection of carbon steel. In the copolymerization process, CTAB served both as a modifier for the modification of GO and a dispersant for the preparation of polyaniline nanofibers. The prepared PANI-f can avoid the accelerated corrosion of steel by conventional synthesis method using hydrochloric acid as medium. The covalent binding between PANI-f and CTGO improved the compatibility of PANI-f-GO with the waterborne epoxy emulsion, which significantly enhance the hydrophobicity and anti-permeability of the coating. The PANI-f-GO waterborne epoxy coating exhibited excellent smart corrosion protection efficiency by catalyzing the formation of passivation film on steel surface. Molecular adsorption energy on Fe(110) and radial distribution function confirmed the chemical adsorption of the PANI-f-GO composite on the steel surface. The superior smart protective performance can be ascribed to the synergistic effects of PANI-f and CTGO.


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