Designed synthesis of chlorine and nitrogen co-doped Ti3C2 MXene quantum dots and their outstanding hydroxyl radical scavenging properties

2021 ◽  
Vol 78 ◽  
pp. 30-37
Author(s):  
Lin Zhao ◽  
Zhao Wang ◽  
Yan Li ◽  
Sen Wang ◽  
Lifeng Wang ◽  
...  
2020 ◽  
Vol 31 (16) ◽  
pp. 165101 ◽  
Author(s):  
Shengqiang Zou ◽  
Fan Guo ◽  
Lin Wu ◽  
Huixiang Ju ◽  
Mingzhong Sun ◽  
...  

Author(s):  
Nguyen Minh Thong Nguyen

- A density functional theory (DFT) study on the hydroxyl radical scavenging properties of Kinsenoside originated from Anoectochilus roxburghii is presented. Two mechanisms, single electron transfer (SET) and hydrogen atom transfer (HAT) are considered. The thermochemical results demonstrate that the SET mechanism is not plausible to occur. With respect to the HAT, the interaction of OH• radical with Kinsenoside is also studied in detail by establishing potential energy surface (PES). This result strongly confirms that the C8H bond decides the radical scavenging activity of Kinsenoside with activation Gibbs free energy (∆G≠) and rate constants (k) of 1.1 kcal/mol and 5.9×10-8 cm3/molecules, respectively


Author(s):  
Birgit Orthen ◽  
Marianne Popp ◽  
Nicholas Smirnoff

Cyclitols are low molecular weight substances which accumulate in plant cells in response to various environmental stress situations, for example drought (Ford 1984), salinity (Gorham et al. 1984), low temperature (Richter et al. 1990).Apart from their more general role in osmotic adjustment, only in the case of salt stress is their mode of function well understood. Cyclitols (e.g. pinitol) accumulate when plants are exposed to increasing salt concentration (Paul & Cockburn 1989) and act as compatible solutes (Sommer et al. 1990) as defined by Brown & Simpson (1972).The significance of cyclitol accumulation in stress adaptation of plants to drought and cold still remains uncertain. However, it is generally accepted that drought and cold as well as several other stress situations lead to an enhanced generation of oxygen free radicals (Elstner 1990; Smirnoff & Colombe 1988), including the hydroxyl radical as the most harmful one. The report by Smirnoff & Cumbes (1989) that myo-inositol is an effective hydroxyl radical scavenger prompted us to test other naturally-occuring cyclitols like pinitol, quebrachitol, 1-D-1-O-methyl-muco-inositol, ononitol and quercitol for their ability to scavenge hydroxyl radicals.


IUBMB Life ◽  
1997 ◽  
Vol 42 (6) ◽  
pp. 1249-1260 ◽  
Author(s):  
Theodore Macrides ◽  
Amal Shihata ◽  
Nicolette Kalafatis ◽  
Paul Wright

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