Geochemical differences of pyrolysis gas of various coal-bearing source rocks and its application in the Sulige gas field, Ordos Basin, China

Light hydrocarbon has abundant geochemical information, but there are few studies on it in Shenmu gas field. Taking Upper Paleozoic in Shenmu gas field as an example, authors use gas chromatography technology to study light hydrocarbon systematically. The results show that (1) The Shenmu gas field is mainly coal-derived gas, which is mixed by partial oil-derived gas due to the experiment data. (2) Based on K1, K2 parameter and Halpern star chart, the Upper Paleozoic gas in Shenmu gas field belongs to the same petroleum system and the depositional environment of natural gas source rocks should be homologous. (3) The source rocks are mainly from terrestrial higher plant origins and belong to swamp facies humic due to methyl cyclohexane index and Mango parameter intersection chart, which excluded the possibility of the Upper Paleozoic limestone as source rocks. (4) The isoheptane ranges from 1.45 to 2.69 with an average of 2.32, and n-heptane ranges from 9.48 to 17.68% with an average of 11.71%, which is below 20%. The maturity of Upper Paleozoic gas in Shenmu gas field is low-normal stage, which is consistent with Ro data. (5) The Upper Paleozoic natural gas in the Shenmu gas field did not experience prolonged migration or secondary changes, thus can be analyzed by light hydrocarbon index precisely.

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Genetic types and sources of Lower Paleozoic natural gas in the Daniudi gas field, Ordos Basin, China

Energy Exploration & Exploitation ◽

10.1177/0144598716687932 ◽

2017 ◽

Vol 35 (2) ◽

pp. 218-236 ◽

Cited By ~ 2

Author(s):

Xiaoqi Wu ◽

Jianhui Zhu ◽

Chunhua Ni ◽

Kuang Li ◽

Yanqing Wang ◽

...

Keyword(s):

Natural Gas ◽

Ordos Basin ◽

Source Rocks ◽

Light Hydrocarbons ◽

Upper Ordovician ◽

Gas Field ◽

Lower Paleozoic ◽

Upper Carboniferous ◽

Associated Gas ◽

The Ordos Basin

The molecular composition, stable carbon and hydrogen isotopes, and light hydrocarbons of the Lower Paleozoic natural gas in the Daniudi gas field in the Ordos Basin were investigated to study the geochemical characteristics. The Lower Paleozoic gas in the Daniudi gas field displays methane contents of 87.41–93.34%, dryness coefficients (C1/C1–5) ranging from 0.886 to 0.978, δ13C1 and δ13C2 values ranging from −40.3 to −36.4‰, with an average of −38.3‰, and from −33.6 to −24.2‰, with an average of −28.4‰, respectively, and δD1 values ranging from −197 to −160‰. The alkane gas generally displays positive carbon and hydrogen isotopic series, and the C7 and C5–7 light hydrocarbons of the Lower Paleozoic gas are dominated by methylcyclohexane and iso-alkanes, respectively. The Lower Paleozoic gas in the Daniudi gas field is mixed from coal-derived and oil-associated gases, similar to that observed in the Jingbian gas field. The oil-associated gas in the Lower Paleozoic gas is secondary oil cracking gas and displays a lower cracking extent than that in the Jingbian gas field. The coal-derived gas in the Lower Paleozoic gas in the Daniudi gas field migrated from the Upper Paleozoic gas through the window area where the iron–aluminum mudstone caprocks in the Upper Carboniferous Benxi Formation were missing. The oil-associated gas in the Lower Paleozoic gas in the Daniudi gas field was probably derived from presalt source rocks in the Lower Ordovician Majiagou Formation rather than the limestone in the Upper Carboniferous Taiyuan Formation. It seems unlikely that the marlstone in the Upper Ordovician Beiguoshan Formation and shale in the Middle Ordovician Pingliang Formation on the western and southwestern margins of the Ordos Basin contributed to the oil-associated gas in the Lower Paleozoic gas in the Daniudi gas field.

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Significance and evolution characteristics of the isobutane/n-butane ratio of natural gas

Energy Exploration & Exploitation ◽

10.1177/0144598719880648 ◽

2019 ◽

Vol 38 (2) ◽

pp. 494-518

Author(s):

Nian Liu ◽

Nansheng Qiu ◽

Zhenming Li ◽

Chuan Cai ◽

Xinjie Shan ◽

...

Keyword(s):

Natural Gas ◽

Mathematical Models ◽

Source Rock ◽

Ordos Basin ◽

The United States ◽

Source Rocks ◽

Initial Increase ◽

Gas Field ◽

Gas Source ◽

Carbonium Ion

In previous studies, two conflicting conclusions existed, which were: (a) the isobutane/n-butane ratio of natural gas increases with the increasing maturity (Ro) of source rocks and (b) decreases with the increasing Ro. In this paper, the correlations between the isobutane/n-butane ratios, dryness of natural gases, and the Ro values of source rocks of 77 gas samples from Cretaceous and Tertiary in Kuqa Depression, Tarim Basin, Triassic Xujiahe Formation in central Sichuan Basin, Carboniferous–Permian in Sulige and Yulin gas field, Ordos Basin, China, and 80 shale gas samples from Mississippian Barnett Shale in the Fort Worth Basin, the United States are analyzed to reveal the evolution of the isobutane/n-butane ratios, then mathematical models of the isobutane/n-butane ratios and Ro are attempted to be established. Results show that the isobutane/n-butane ratio initially increases and then decreases with increasing Ro, both coal-derived gas and oil-type gas. Diverse types of kerogens may be responsible for the different corresponding Ro values when the isobutane/n-butane ratios of gases reach their maximum values. The initial increase in the isobutane/n-butane ratios with increasing Ro is the reason that isobutane is mainly generated at a higher rate by carbonium ion reaction of α-olefins with protons during kerogen primary cracking at lower maturity, whereas free radical reactions to form n-butane relatively quickly during oil cracking at higher maturity and isobutane cracked at a higher rate during the wet gas cracking stage may result in the terminal decreases in the isobutane/n-butane ratios. Besides, mathematical models of the isobutane/n-butane ratios of different types of natural gas and maturity are established. Therefore, the maturity of gas source rock can be obtained quickly based on the models using the isobutane/n-butane ratio combined with other component information (such as dryness, wetness, etc.), which is of great significance to the characterization of natural gas maturity and gas source rock correlation.

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