scholarly journals Genetic types and sources of Lower Paleozoic natural gas in the Daniudi gas field, Ordos Basin, China

2017 ◽  
Vol 35 (2) ◽  
pp. 218-236 ◽  
Author(s):  
Xiaoqi Wu ◽  
Jianhui Zhu ◽  
Chunhua Ni ◽  
Kuang Li ◽  
Yanqing Wang ◽  
...  
Keyword(s):  
Natural Gas ◽  
Ordos Basin ◽  
Source Rocks ◽  
Light Hydrocarbons ◽  
Upper Ordovician ◽  
Gas Field ◽  
Lower Paleozoic ◽  
Upper Carboniferous ◽  
Associated Gas ◽  
The Ordos Basin

The molecular composition, stable carbon and hydrogen isotopes, and light hydrocarbons of the Lower Paleozoic natural gas in the Daniudi gas field in the Ordos Basin were investigated to study the geochemical characteristics. The Lower Paleozoic gas in the Daniudi gas field displays methane contents of 87.41–93.34%, dryness coefficients (C1/C1–5) ranging from 0.886 to 0.978, δ13C1 and δ13C2 values ranging from −40.3 to −36.4‰, with an average of −38.3‰, and from −33.6 to −24.2‰, with an average of −28.4‰, respectively, and δD1 values ranging from −197 to −160‰. The alkane gas generally displays positive carbon and hydrogen isotopic series, and the C7 and C5–7 light hydrocarbons of the Lower Paleozoic gas are dominated by methylcyclohexane and iso-alkanes, respectively. The Lower Paleozoic gas in the Daniudi gas field is mixed from coal-derived and oil-associated gases, similar to that observed in the Jingbian gas field. The oil-associated gas in the Lower Paleozoic gas is secondary oil cracking gas and displays a lower cracking extent than that in the Jingbian gas field. The coal-derived gas in the Lower Paleozoic gas in the Daniudi gas field migrated from the Upper Paleozoic gas through the window area where the iron–aluminum mudstone caprocks in the Upper Carboniferous Benxi Formation were missing. The oil-associated gas in the Lower Paleozoic gas in the Daniudi gas field was probably derived from presalt source rocks in the Lower Ordovician Majiagou Formation rather than the limestone in the Upper Carboniferous Taiyuan Formation. It seems unlikely that the marlstone in the Upper Ordovician Beiguoshan Formation and shale in the Middle Ordovician Pingliang Formation on the western and southwestern margins of the Ordos Basin contributed to the oil-associated gas in the Lower Paleozoic gas in the Daniudi gas field.

scholarly journals Light hydrocarbon geochemical characteristics and their application in Upper Paleozoic, Shenmu gas field, Ordos Basin

2016 ◽  
Vol 35 (1) ◽  
pp. 103-121 ◽  
Author(s):  
Wenxue Han ◽  
Shizhen Tao ◽  
Guoyi Hu ◽  
Weijiao Ma ◽  
Dan Liu ◽  
...  
Keyword(s):  
Natural Gas ◽  
Ordos Basin ◽  
Light Hydrocarbon ◽  
Source Rocks ◽  
Higher Plant ◽  
Gas Field ◽  
Gas Source ◽  
Upper Paleozoic ◽  
Methyl Cyclohexane ◽  
Normal Stage

Light hydrocarbon has abundant geochemical information, but there are few studies on it in Shenmu gas field. Taking Upper Paleozoic in Shenmu gas field as an example, authors use gas chromatography technology to study light hydrocarbon systematically. The results show that (1) The Shenmu gas field is mainly coal-derived gas, which is mixed by partial oil-derived gas due to the experiment data. (2) Based on K1, K2 parameter and Halpern star chart, the Upper Paleozoic gas in Shenmu gas field belongs to the same petroleum system and the depositional environment of natural gas source rocks should be homologous. (3) The source rocks are mainly from terrestrial higher plant origins and belong to swamp facies humic due to methyl cyclohexane index and Mango parameter intersection chart, which excluded the possibility of the Upper Paleozoic limestone as source rocks. (4) The isoheptane ranges from 1.45 to 2.69 with an average of 2.32, and n-heptane ranges from 9.48 to 17.68% with an average of 11.71%, which is below 20%. The maturity of Upper Paleozoic gas in Shenmu gas field is low-normal stage, which is consistent with Ro data. (5) The Upper Paleozoic natural gas in the Shenmu gas field did not experience prolonged migration or secondary changes, thus can be analyzed by light hydrocarbon index precisely.

scholarly journals Lower Paleozoic source rocks and natural gas origins in Ordos Basin, NW China

2016 ◽  
Vol 43 (4) ◽  
pp. 591-601 ◽  
Author(s):  
Dan LIU ◽  
Wenzheng ZHANG ◽  
Qingfen KONG ◽  
Ziqi FENG ◽  
Chenchen FANG ◽  
...  
Keyword(s):  
Natural Gas ◽  
Ordos Basin ◽  
Source Rocks ◽  
Lower Paleozoic ◽  
Nw China

scholarly journals Pore Structures of the Lower Permian Taiyuan Shale and Limestone in the Ordos Basin and the Significance to Unconventional Natural Gas Generation and Storage

Geofluids ◽  
2022 ◽  
Vol 2022 ◽  
pp. 1-16
Author(s):  
L. Zhang ◽  
Q. Zhao ◽  
C. Wu ◽  
Z. Qiu ◽  
Q. Zhang ◽  
...  
Keyword(s):  
Organic Matter ◽  
Natural Gas ◽  
Shale Gas ◽  
Pore Volume ◽  
Ordos Basin ◽  
Source Rocks ◽  
Taiyuan Formation ◽  
Oil Generation ◽  
Unconventional Natural Gas ◽  
The Ordos Basin

In the Ordos Basin, multiple sets of coal seams, organic-rich shale, and limestone are well developed in the Permian Taiyuan Formation, which are favorable targets for collaborative exploration of various types of unconventional natural gas resources, including coalbed methane, shale gas, and tight gas. In this study, core samples from the Permian Taiyuan Formation in the eastern margin of the Ordos Basin were used to carry out a series of testing and analysis, such as the organic matter characteristics, the mineral composition, and the pore development characteristics. In the shale of the Taiyuan Formation, the total organic carbon (TOC) content is relatively high, with an average of 5.38%. A thin layer of black shale is developed on the top of the Taiyuan Formation, which is relatively high in TOC content, with an average of 9.72%. The limestone in the Taiyuan Formation is also relatively high in organic matter abundance, with an average of 1.36%, reaching the lower limit of effective source rocks (>1%), being good source rocks. In the shale of the Taiyuan Formation, various types of pores are well developed, with relatively high overall pore volume and pore-specific surface area, averaging 0.028 ml/g and 13.28 m2/g, respectively. The pore types are mainly mineral intergranular pores and clay mineral interlayer fractures, while organic matter-hosted pores are poorly developed. The limestone of the Taiyuan Formation is relatively tight, with lower pore volume and pore-specific surface area than those of shale, averaging 0.0106 ml/g and 2.72 m2/g, respectively. There are mainly two types of pores, namely, organic matter-hosted pores and carbonate mineral dissolution pores, with a high surface pore rate. The organic matter in the limestone belongs to the oil-generation kerogen. During thermal evolution, the organic matter has gone through the oil-generation window, generating a large number of liquid hydrocarbons, which were cracked into a large number of gaseous hydrocarbons at the higher mature stage. As a result, a large number of organic matter-hosted pores were generated. The study results show that in the Ordos Basin, the shale and limestone of the Permian Taiyuan Formation have great potential in terms of unconventional natural gas resources, providing a good geological basis for the collaborative development of coal-bearing shale gas and tight limestone gas in the Taiyuan Formation.

scholarly journals Significance and evolution characteristics of the isobutane/n-butane ratio of natural gas

2019 ◽  
Vol 38 (2) ◽  
pp. 494-518
Author(s):  
Nian Liu ◽  
Nansheng Qiu ◽  
Zhenming Li ◽  
Chuan Cai ◽  
Xinjie Shan ◽  
...  
Keyword(s):  
Natural Gas ◽  
Mathematical Models ◽  
Source Rock ◽  
Ordos Basin ◽  
The United States ◽  
Source Rocks ◽  
Initial Increase ◽  
Gas Field ◽  
Gas Source ◽  
Carbonium Ion

In previous studies, two conflicting conclusions existed, which were: (a) the isobutane/n-butane ratio of natural gas increases with the increasing maturity (Ro) of source rocks and (b) decreases with the increasing Ro. In this paper, the correlations between the isobutane/n-butane ratios, dryness of natural gases, and the Ro values of source rocks of 77 gas samples from Cretaceous and Tertiary in Kuqa Depression, Tarim Basin, Triassic Xujiahe Formation in central Sichuan Basin, Carboniferous–Permian in Sulige and Yulin gas field, Ordos Basin, China, and 80 shale gas samples from Mississippian Barnett Shale in the Fort Worth Basin, the United States are analyzed to reveal the evolution of the isobutane/n-butane ratios, then mathematical models of the isobutane/n-butane ratios and Ro are attempted to be established. Results show that the isobutane/n-butane ratio initially increases and then decreases with increasing Ro, both coal-derived gas and oil-type gas. Diverse types of kerogens may be responsible for the different corresponding Ro values when the isobutane/n-butane ratios of gases reach their maximum values. The initial increase in the isobutane/n-butane ratios with increasing Ro is the reason that isobutane is mainly generated at a higher rate by carbonium ion reaction of α-olefins with protons during kerogen primary cracking at lower maturity, whereas free radical reactions to form n-butane relatively quickly during oil cracking at higher maturity and isobutane cracked at a higher rate during the wet gas cracking stage may result in the terminal decreases in the isobutane/n-butane ratios. Besides, mathematical models of the isobutane/n-butane ratios of different types of natural gas and maturity are established. Therefore, the maturity of gas source rock can be obtained quickly based on the models using the isobutane/n-butane ratio combined with other component information (such as dryness, wetness, etc.), which is of great significance to the characterization of natural gas maturity and gas source rock correlation.

Quantitative identification and research of mixed-source natural gas-example of natural gas in Jingbian gas field

2014 ◽  
Vol 11 (2) ◽  
pp. 147-156
Author(s):  
Yifeng Wang ◽  
Jian Li ◽  
Jianfa Chen ◽  
Chengshan Li
Keyword(s):  
Natural Gas ◽  
Source Rock ◽  
Ordos Basin ◽  
Weighted Average ◽  
Gas Field ◽  
Lower Paleozoic ◽  
Upper Paleozoic ◽  
Geological Conditions ◽  
Weathered Crust ◽  
Geochemistry Characteristics

It is shown in natural gas proportion mixing experiments that a mixed-source natural gas is the physical combination of end member gas. Both the carbon and hydrogen isotopes in the mixed-source natural gas can be expressed by the weighted average of corresponding components content and isotopes of end member gas. Under certain geological setting, the selection of end member gas is the key to mixed-source ratio calculation. Then, it's better to estimate the mixed-source ratio with δ13C1 and component data according to the weighted average calculation formula. The analysis on natural gas geochemistry characteristics show that the natural gas extracted from Jingbian Gas Field in the Ordos Basin is mainly an upper Paleozoic coal-derived gas. In the analysis of geological conditions for reservoir forming and characteristics of natural gas, natural gas from Longtan 1 Well and Tao 6 Well were selected as the end member gases of lower Paleozoic oil-type gas and upper Paleozoic coal-type gas respectively to calculate the mixed-source ratio of natural gas in Jingbian Gas Field. The ratio of upper Paleozoic coal-derived gas mostly accounts for over 70% and its average ratio reaches 81%. Therefore, the exploration of natural gas of Ordos Basin should be focused on the upper palaeozoic coal source rock, and attention should be paid to the matching of coal source rock in the exploration of weathered crust gas deposit.

Using Light Hydrocarbons to Identify the Depositional Environment of Source Rocks in the Ordos Basin, Central China

2015 ◽  
Vol 33 (6) ◽  
pp. 869-890 ◽  
Author(s):  
Dan Liu ◽  
Cong Yu ◽  
Shipeng Huang ◽  
Chenchen Fang ◽  
Ziqi Feng ◽  
...  
Keyword(s):  
Depositional Environment ◽  
Ordos Basin ◽  
Source Rocks ◽  
Central China ◽  
Light Hydrocarbons ◽  
The Ordos Basin
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