Effect of natural gas components on its flame temperature, equilibrium combustion products and thermodynamic properties

2017 ◽  
Vol 45 ◽  
pp. 456-473 ◽  
Author(s):  
Hasan Kayhan Kayadelen

It has been shown that in an m.h.d. generator, acoustic waves can grow due to the coupling of fluctuations in electrical conductivity, Hall parameter and thermodynamic properties of the gas, with the ohmic dissipation and electromagnetic body forces. A new analysis of this phenomenon is presented in which waves travelling at an arbitrary angle to the flow direction in a plane perpendicular to the magnetic field are considered. In contrast to McCune’s (1964) treatment the thermodynamic properties are not restricted to perfect gas laws; and the condition for spatially and temporally growing waves is examined using a general dispersion relation which includes both these types of wave. We consider in detail (i) stationary waves in supersonic flow, and (ii) travelling waves in the subsonic flow found in the G.E.G.B. 200 MW thermal input generator being built at Marchwood, and a possible power station m.h.d. generator. It is found that the waves in the 200 MW rig which burns kerosene in oxygen will be damped. But in an oil-air combustion products generator for Hall parameters of order 3 or greater, it is found that stationary waves which grow rapidly may occur at Mach numbers greater than about 1-7; and in subsonic flow waves propagating antiparallel to the steady current vector may be amplified, though the growth rate is not excessive. In noble gas m.h.d. generators these waves are more unstable than in the oil, air combustion products generator.


Author(s):  
Brian Hollon ◽  
Erlendur Steinthorsson ◽  
Adel Mansour ◽  
Vincent McDonell ◽  
Howard Lee

This paper discusses the development and testing of a full-scale micro-mixing lean-premix injector for hydrogen and syngas fuels that demonstrated ultra-low emissions and stable operation without flashback for high-hydrogen fuels at representative full-scale operating conditions. The injector was fabricated using Macrolamination technology, which is a process by which injectors are manufactured from bonded layers. The injector utilizes sixteen micro-mixing cups for effective and rapid mixing of fuel and air in a compact package. The full scale injector is rated at 1.3 MWth when operating on natural gas at 12.4 bar (180 psi) combustor pressure. The injector operated without flash back on fuel mixtures ranging from 100% natural gas to 100% hydrogen and emissions were shown to be insensitive to operating pressure. Ultra-low NOx emissions of 3 ppm were achieved at a flame temperature of 1750 K (2690 °F) using a fuel mixture containing 50% hydrogen and 50% natural gas by volume with 40% nitrogen dilution added to the fuel stream. NOx emissions of 1.5 ppm were demonstrated at a flame temperature over 1680 K (2564 °F) using the same fuel mixture with only 10% nitrogen dilution, and NOx emissions of 3.5 ppm were demonstrated at a flame temperature of 1730 K (2650 °F) with only 10% carbon dioxide dilution. Finally, using 100% hydrogen with 30% carbon dioxide dilution, 3.6 ppm NOx emissions were demonstrated at a flame temperature over 1600 K (2420 °F). Superior operability was achieved with the injector operating at temperatures below 1470 K (2186 °F) on a fuel mixture containing 87% hydrogen and 13% natural gas. The tests validated the micro-mixing fuel injector technology and the injectors show great promise for use in future gas turbine engines operating on hydrogen, syngas or other fuel mixtures of various compositions.


Author(s):  
O.V. Kalashnikov ◽  
S.V. Budniak ◽  
Yu.V. Ivanov ◽  
Yu.M. Belyansky ◽  
N.O. Aptulina ◽  
...  

The experimental and calculated according to program systems GasCondOil, Aspen-HYSYS and PRO-II compositions of the gas — liquid phases (hydrocarbon and aqueous solutions) and their thermodynamic properties are compared, as well as the accuracy of technological calculations of field pipelines and natural gas and oil treatment processes. It is shown that some of the field technological processes, calculated by the program system GasCondOil, are not modeled on Aspen-HYSYS. Bibl. 16, Fig. 9, Tab. 15.


2012 ◽  
Vol 245 ◽  
pp. 346-351
Author(s):  
Radu Dan Rugescu ◽  
Florin Radu Bacaran

The observation that the chemical equilibrium between the combustion products of solid propellant samples within static calorimeters is unexpectedly freezing at high temperatures is proved through a general numerical simulation of the isochoric cooling with chemical reactions between the gaseous products. A proprietary, direct linearization method of thermochemical computation is used that enables following any chemical reaction in equilibrium with high convergence. The observed chemical freezing within calorimeters is proved.


Sign in / Sign up

Export Citation Format

Share Document