scholarly journals Synthesis, structural characterization and catalytic activity of indenyl complexes of ruthenium bearing fluorinated phosphine ligands

2017 ◽  
Vol 847 ◽  
pp. 41-53 ◽  
Author(s):  
Matthew J. Stark ◽  
Michael J. Shaw ◽  
Arghavan Fadamin ◽  
Nigam P. Rath ◽  
Eike B. Bauer
Keyword(s):  
Catalytic Activity ◽  
Structural Characterization ◽  
Phosphine Ligands ◽  
Indenyl Complexes

Diruthenium tetracarbonyl sawhorse complexes bearing N-heterocylic carbene and phosphine ligands: Synthesis, structural characterization, and catalytic activity

2016 ◽  
Vol 802 ◽  
pp. 1-8 ◽  
Author(s):  
Thomas N. Rohrabaugh ◽  
Joshua C. Doverspike ◽  
Steven J. Geib ◽  
Evan D. Sawyer ◽  
Mitchell R. Stibbard ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Structural Characterization ◽  
Phosphine Ligands

Synthesis, structural characterization and catalytic activity of chlororuthenium(II) complexes with substituted Schiff base/phosphine ancillary ligands

2020 ◽  
Vol 75 (9-10) ◽  
pp. 851-857
Author(s):  
Chong Chen ◽  
Fule Wu ◽  
Jiao Ji ◽  
Ai-Quan Jia ◽  
Qian-Feng Zhang
Keyword(s):  
Schiff Base ◽  
Catalytic Activity ◽  
Structural Characterization ◽  
Room Temperature ◽  
Molecular Structures ◽  
Cationic Complex ◽  
Neutral Complex ◽  
Ancillary Ligands ◽  
X Ray ◽  
X Ray Crystallography

AbstractTreatment of [(η6-p-cymene)RuCl2]2 with one equivalent of chlorodiphenylphosphine in tetrahydrofuran at reflux afforded a neutral complex [(η6-p-cymene)RuCl2(κ1-P-PPh2OH)] (1). Similarly, the reaction of [Ru(bpy)2Cl2·2H2O] (bpy = 2,2′-bipyridine) and chlorodiphenylphosphine in methanol gave a cationic complex [Ru(bpy)2Cl(κ1-P-PPh2OCH3)](PF6) (2), while treatment of [RuCl2(PPh3)3] with [2-(C5H4N)CH=N(CH2)2N(CH3)2] (L1) in tetrahydrofuran at room temperature afforded a ruthenium(II) complex [Ru(PPh3)Cl2(κ3-N,N,N-L1)] (3). Interaction of the chloro-bridged complex [Ru(CO)2Cl2]n with one equivalent of [Ph2P(o-C6H4)CH=N(CH2)2N(CH3)2] (L2) led to the isolation of [Ru(CO)Cl2(κ3-P,N,N-L2)] (4). The molecular structures of the ruthenium(II) complexes 1–4 have been determined by single-crystal X-ray crystallography. The properties of the ruthenium(II) complex 4 as a hydrogenation catalyst for acetophenone were also tested.

Synthesis and structural characterization of binuclear silver(I) complexes bridged by three polydentate phosphine ligands

1999 ◽  
Vol 284 (2) ◽  
pp. 278-283 ◽  
Author(s):  
Shan-Ming Kuang ◽  
Li-Ming Zhang ◽  
Zheng-Zhi Zhang ◽  
Bo-Mu Wu ◽  
Thomas C.W. Mak
Keyword(s):  
Structural Characterization ◽  
Phosphine Ligands ◽  
Polydentate Phosphine Ligands

Homolysis of the Eu−N Bond. Synthesis, Structural Characterization, and Catalytic Activity of Novel Europium(II) Complexes

2003 ◽  
Vol 22 (17) ◽  
pp. 3546-3552 ◽  
Author(s):  
Shaowu Wang ◽  
Shuangliu Zhou ◽  
Enhong Sheng ◽  
Meihua Xie ◽  
Kehua Zhang ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Structural Characterization ◽  
The Eu

scholarly journals Preparation of monocarbonyl ruthenium complexes bearing bidentate nitrogen and phosphine ligands and their catalytic activity in carbonyl compound reduction

2019 ◽  
Vol 48 (33) ◽  
pp. 12560-12576 ◽  
Author(s):  
Steven Giboulot ◽  
Clara Comuzzi ◽  
Alessandro Del Zotto ◽  
Rosario Figliolia ◽  
Giovanna Lippe ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Carbonyl Compound ◽  
Ruthenium Complexes ◽  
Ruthenium Catalysts ◽  
Phosphine Ligands ◽  
Diphosphine Ligands ◽  
Straightforward Approach

A series of novel monocarbonyl ruthenium catalysts containing bidentate dinitrogen or/and diphosphine ligands are easily obtained through a general and straightforward approach.

Uncommon Anionic Dioxorhenium(V) and Neutral Monooxorhenium(V) Mixed-Ligand Complexes Containing Heterofunctionalized Phosphine Ligands:  Syntheses and Structural Characterization

1996 ◽  
Vol 35 (21) ◽  
pp. 6221-6229 ◽  
Author(s):  
Cristina Bolzati ◽  
Francesco Tisato ◽  
Fiorenzo Refosco ◽  
Giuliano Bandoli ◽  
Alessandro Dolmella
Keyword(s):  
Structural Characterization ◽  
Mixed Ligand ◽  
Phosphine Ligands ◽  
Mixed Ligand Complexes

scholarly journals Complexes of the tripodal phosphine ligands PhSi(XPPh2)3(X = CH2, O): synthesis, structure and catalytic activity in the hydroboration of CO2

2016 ◽  
Vol 45 (37) ◽  
pp. 14774-14788 ◽  
Author(s):  
Alicia Aloisi ◽  
Jean-Claude Berthet ◽  
Caroline Genre ◽  
Pierre Thuéry ◽  
Thibault Cantat
Keyword(s):  
Catalytic Activity ◽  
Coordination Chemistry ◽  
Electronic Properties ◽  
Phosphine Ligands ◽  
Phosphorus Ligands ◽  
The Impact

The coordination chemistry of Fe2+, Co2+and Cu+ions was explored with the ligands PhSi{CH2PPh2}3(1) and PhSi{OPPh2}3(2), so as to evaluate the impact of the electronic properties of the tripodal phosphorus ligands on the structure and reactivity of the corresponding complexes.

Air-stable Pd(0) catalyst bearing dual phosphine ligands: a detailed evaluation of air stability and catalytic property in cross-coupling reactions

2020 ◽  
Vol 49 (36) ◽  
pp. 12814-12819
Author(s):  
Ryota Sato ◽  
Takaki Kanbara ◽  
Junpei Kuwabara
Keyword(s):  
Catalytic Activity ◽  
Catalytic Property ◽  
Cross Coupling ◽  
Phosphine Ligands ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Donor And Acceptor ◽  
Detailed Evaluation ◽  
Good Catalytic Activity

The Pd(0) complex bearing donor and acceptor phosphine ligands shows long-term air stability and good catalytic activity even in a reaction with a relatively inactive substrate.

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