Synthesis of fcc Mg–Ti–H alloys by high energy ball milling: Structure and electrochemical hydrogen storage properties

2010 ◽  
Vol 195 (13) ◽  
pp. 4370-4374 ◽  
Author(s):  
Steeve Rousselot ◽  
Daniel Guay ◽  
Lionel Roué
2021 ◽  
Vol 21 (8) ◽  
pp. 4353-4361
Author(s):  
Myoung Youp Song ◽  
Seong Ho Lee ◽  
Young Jun Kwak ◽  
Eunho Choi

TiCl3 was chosen as an additive to increase hydriding and dehydriding rates of Mg. In our previous works, we found that the optimum percentage of additives that improved the hydriding and dehydriding features of Mg was approximately ten. Specimens consisting of 90 wt% Mg and 10 wt% TiCl3 (named Mg–10TiCl3) were prepared by high-energy ball milling in hydrogen. The specimens’ hydriding and dehydriding properties were then studied. Mg–10TiCl3 had an effective hydrogenstorage capacity (the quantity of hydrogen absorbed in 60 min) of approximately 7.2 wt% at 593 K under 12 bar H2 at the second cycle. After high-energy ball milling in hydrogen, Mg–10TiCl3 contained Mg, β-MgH2, and small amounts of γ-MgH2 and TiH1.924. TiH1.924 remained undercomposed even after dehydriding at 623 K in a vacuum for 2 h. The hydriding and dehydriding properties of Mg–10TiCl3 were compared with those of other specimens such as Mg–10Fe2O3, Mg–10NbF5, and Mg–5Fe2O3–5Ni, for which the hydrogen-storage properties were previously reported.


2010 ◽  
Vol 35 (9) ◽  
pp. 4027-4040 ◽  
Author(s):  
Cheng-Hong Liu ◽  
Yi-Chia Kuo ◽  
Bing-Hung Chen ◽  
Chan-Li Hsueh ◽  
Kuo-Jen Hwang ◽  
...  

RSC Advances ◽  
2016 ◽  
Vol 6 (96) ◽  
pp. 93238-93244 ◽  
Author(s):  
Xiaobo Li ◽  
Shuchao Sun ◽  
Jianjiao Zhang ◽  
Kan Luo ◽  
Peng Gao ◽  
...  

In this work an archetypical hybrid material has been prepared by the reaction of an inorganic CoB noncrystal with graphene by a high-energy ball-milling process, which showed an enhanced electrochemical hydrogen storage ability induced by the Co–B–C structure.


2005 ◽  
Vol 386 (1-2) ◽  
pp. 211-216 ◽  
Author(s):  
Hayao Imamura ◽  
Kazuo Masanari ◽  
Mitsuya Kusuhara ◽  
Hikaru Katsumoto ◽  
Takeshi Sumi ◽  
...  

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