Dynamic electrochemical impedance spectroscopy of Pt/C-based membrane-electrode assemblies subjected to cycling protocols

2013 ◽  
Vol 242 ◽  
pp. 447-454 ◽  
Author(s):  
Mahdi Darab ◽  
Per Kristian Dahlstrøm ◽  
Magnus Skinlo Thomassen ◽  
Frode Seland ◽  
Svein Sunde
RSC Advances ◽  
2016 ◽  
Vol 6 (83) ◽  
pp. 80275-80285 ◽  
Author(s):  
Bhavana Rikhari ◽  
S. Pugal Mani ◽  
N. Rajendran

In the present work, dynamic electrochemical impedance spectroscopy (DEIS) was used to investigate the corrosion behavior of polypyrrole (PPy)-coated titanium (Ti) in simulated body fluid (SBF) solution.


2018 ◽  
Vol 42 (17) ◽  
pp. 14394-14409 ◽  
Author(s):  
S. Pugal Mani ◽  
Bhavana Rikhari ◽  
Perumal Agilan ◽  
N. Rajendran

In the present investigation, the corrosion behavior of TiN-coated 316L SS was evaluated for use in a proton-exchange membrane fuel cell using dynamic electrochemical impedance spectroscopy (DEIS).


2013 ◽  
Vol 41 (5) ◽  
pp. 3261-3273
Author(s):  
Houria Nacer ◽  
Laila Afia ◽  
Rachid Salghi ◽  
Rachid Touzani ◽  
Laid Bouzenada ◽  
...  

Materials ◽  
2018 ◽  
Vol 11 (8) ◽  
pp. 1368 ◽  
Author(s):  
Stefania Siracusano ◽  
Stefano Trocino ◽  
Nicola Briguglio ◽  
Vincenzo Baglio ◽  
Antonino Aricò

Membrane–electrode assemblies (MEAs) designed for a polymer electrolyte membrane (PEM) water electrolyser based on a short-side chain (SSC) perfluorosulfonic acid (PFSA) membrane, Aquivion®, and an advanced Ir-Ru oxide anode electro-catalyst, with various cathode and anode noble metal loadings, were investigated. Electrochemical impedance spectroscopy (EIS), in combination with performance and durability tests, provided useful information to identify rate-determining steps and to quantify the impact of the different phenomena on the electrolysis efficiency and stability characteristics as a function of the MEA properties. This technique appears to be a useful diagnostic tool to individuate different phenomena and to quantify their effect on the performance and degradation of PEM electrolysis cells.


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