Functionalized SBA-15 supported nickel (II)–oxime–imine catalysts for liquid phase oxidation of olefins under solvent-free conditions

The catalytic performance of Mn3O4 supported on carbon nanotubes (CNTs) in the liquid-phase oxidation of toluene to benzyl alcohol and benzaldehyde was studied. The supported catalysts were characterized by X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), N2 adsorption–desorption isotherms and ICP-MS. The results demonstrate that Mn3O4 nanoparticles loaded on CNTs performed better compared with pristine Mn3O4 or CNTs. The main reason for the increased catalytic activity is the dispersion and loading of Mn3O4 in CNTs. By optimizing the reaction temperature, reaction time, catalyst quality, oxygen flow rate and initiator dosage, the optimum reaction conditions were obtained. Using tert-butyl hydroperoxide (TBHP) as the initiator and oxygen as the oxidant, the toluene conversion rate was as high as 24.63%, and benzyl alcohol and benzaldehyde selectivity was 90.49%. The good stability of the catalyst was confirmed by repeating the experiment for four cycles and observing no significant changes in its performance.

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Heterogeneous Catalysis in the Liquid-phase Oxidation of Olefins. IV. The Activity of a Supported Vanadium or Chromium Oxide Catalyst in the Decomposition oft-Butyl Hydroperoxide

Bulletin of the Chemical Society of Japan ◽

10.1246/bcsj.53.2103 ◽

1980 ◽

Vol 53 (8) ◽

pp. 2103-2110

Author(s):

Katsuomi Takehira ◽

Takashi Hayakawa ◽

Toshio Ishikawa

Keyword(s):

Heterogeneous Catalysis ◽

Liquid Phase ◽

Chromium Oxide ◽

Oxide Catalyst ◽

Liquid Phase Oxidation ◽

Butyl Hydroperoxide ◽

Phase Oxidation ◽

Oxidation Of Olefins

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Novel solvent free liquid-phase oxidation of β-pinene over heterogeneous catalysts based on Fe3−xMxO4 (M=Co and Mn)

Applied Catalysis A General ◽

10.1016/j.apcata.2004.04.005 ◽

2004 ◽

Vol 269 (1-2) ◽

pp. 117-121 ◽

Cited By ~ 25

Author(s):

Luciano Menini ◽

Márcio J. da Silva ◽

Maria F.F. Lelis ◽

José D. Fabris ◽

Rochel M. Lago ◽

...

Keyword(s):

Liquid Phase ◽

Heterogeneous Catalysts ◽

Solvent Free ◽

Liquid Phase Oxidation ◽

Phase Oxidation

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A reusable CuII based metal–organic framework as a catalyst for the oxidation of olefins

Catalysis Science & Technology ◽

10.1039/c4cy00152d ◽

2014 ◽

Vol 4 (8) ◽

pp. 2599-2607 ◽

Cited By ~ 54

Author(s):

Patricio Cancino ◽

Verónica Paredes-García ◽

Pedro Aguirre ◽

Evgenia Spodine

Keyword(s):

Liquid Phase ◽

Heterogeneous Catalyst ◽

Metal Organic Framework ◽

Liquid Phase Oxidation ◽

Phase Oxidation ◽

Oxidation Of Olefins ◽

Metal Organic ◽

Organic Framework

The metal–organic framework [Cu2(bipy)2(btec)]∞ was used as a heterogeneous catalyst in the liquid phase oxidation of styrene and cyclohexene with tert-butylhydroperoxide (TBHP) as the oxidant either in water–dichloroethane or n-decane medium.

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