Thermal induced spin transition in a series of iron(II) layered inorganic-organic solids. Role of the intermolecular interactions in the interlayer region

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Mononuclear complex [Fe(3-bpp)2](CF3COO)2 exhibits a thermal (HS + HS) ⇋ (HS + LS) transition at ∼226 K which is not associated with any crystallographic transition.


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