Solid-state photoluminescence, energy transfer mechanism and optical band gap of two 4f-5d complexes with 1-D chain-like structure

2020 ◽  
Vol 292 ◽  
pp. 121700
Author(s):  
Wen-Tong Chen
Keyword(s):  
Energy Transfer ◽  
Solid State ◽  
Band Gap ◽  
Optical Band Gap ◽  
Transfer Mechanism ◽  
Energy Transfer Mechanism

scholarly journals Photophysical properties and energy transfer mechanism of a praseodymium compound with a two-dimensional layer

2020 ◽  
Vol 44 (5-6) ◽  
pp. 343-348
Author(s):  
Wen-Tong Chen
Keyword(s):  
Energy Transfer ◽  
Solid State ◽  
Hydrothermal Reaction ◽  
Photophysical Properties ◽  
Transfer Mechanism ◽  
Energy Transfer Mechanism ◽  
Two Dimensional ◽  
Monoclinic System ◽  
Reflectance Measurement ◽  
Praseodymium Complex

A hydrothermal reaction results in the formation of a novel [Pr2(2,5-PA)2(2,5-HPA)2(H2O)4] n·2 nH2O complex (2,5-H2PA = 2,5-pyridinedicarboxylic acid). The complex is structurally characterized by single-crystal X-ray diffraction and crystallizes in the space group P21 of the monoclinic system with two formula units in one cell. This praseodymium complex is characterized by a two-dimensional layered structure. A solid-state photoluminescence experiment reveals that the praseodymium complex shows an emission in the red region. The complex has Commission Internationale de I’Éclairage chromaticity coordinates of 0.5495 and 0.4492. The photoluminescence emission bands could be assigned to the characteristic emission of the 4 f electron intrashell transition of the 3 P0 → 3 H5, 1 D2 → 3 H4, 3 P0 → 3 H6, 3 P0 → 3 F2, and 3 P1 → 3 F3 of the Pr3+ ions. The energy transfer mechanism is explained by the energy level diagrams of the praseodymium ions and the 2,5-H2PA ligand. A solid-state diffuse reflectance measurement shows that the complex possesses a wide optical band gap of 3.48 eV.

scholarly journals Synthesis, structure, photophysical properties, and energy transfer mechanism of an erbium–mercury compound

2020 ◽  
Vol 44 (11-12) ◽  
pp. 727-732
Author(s):  
Wen-Tong Chen
Keyword(s):  
Energy Transfer ◽  
Solid State ◽  
Hydrothermal Reaction ◽  
Isonicotinic Acid ◽  
Photophysical Properties ◽  
Transfer Mechanism ◽  
Mercury Compound ◽  
Energy Transfer Mechanism ◽  
Reflectance Measurement ◽  
Erbium Ions

A hydrothermal reaction leads to the formation of a novel erbium–mercury compound [Er(IA)3(H3O)(H2O)] n(0.5 nHg2I6) (1) (HIA = isonicotinic acid). The compound has been characterized by single-crystal X-ray diffraction. It is characteristic of a one-dimensional chain-like structure and a two-dimensional supramolecular layer. A solid-state photoluminescence experiment reveals that this compound displays upconversion green photoluminescence. The photoluminescence emission peaks can be attributed to the 4 G11/2 → 4 I15/2, 4 F7/2 → 4 I15/2, and 2 H11/2 → 4 I15/2 of the Er3+ ions. The energy transfer mechanism is consistent with the energy-level diagrams of the erbium ions and isonicotinic acid ligand. This compound possesses Commission Internationale de I'Éclairage chromaticity coordinates of 0.1755 and 0.5213. A solid-state diffuse reflectance measurement reveals that this compound features a narrow optical band gap of 1.97 eV.

Energy transfer mechanism of supersonic jet noise through rectangular nozzles

2017 ◽  
Vol 65 (2) ◽  
pp. 110-120 ◽  
Author(s):  
Zhe Chen ◽  
Jiu-Hui Wu ◽  
A-Dan Ren ◽  
Xin Chen ◽  
Zhen Huang
Keyword(s):  
Energy Transfer ◽  
Supersonic Jet ◽  
Jet Noise ◽  
Transfer Mechanism ◽  
Energy Transfer Mechanism ◽  
Supersonic Jet Noise

Luminescence Properties and energy transfer mechanism of Eu3+ and Tm3+ Co-doped AlN Thin Films

2021 ◽  
pp. 118082
Author(s):  
Hai Ma ◽  
Xiaodan Wang ◽  
Feifei Chen ◽  
Jiafan Chen ◽  
Xionghui Zeng ◽  
...  
Keyword(s):  
Thin Films ◽  
Energy Transfer ◽  
Transfer Mechanism ◽  
Luminescence Properties ◽  
Energy Transfer Mechanism ◽  
Co Doped

scholarly journals Polymer Thermal Treatment Production of Cerium Doped Willemite Nanoparticles: An Analysis of Structure, Energy Band Gap and Luminescence Properties

Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1118
Author(s):  
Ibrahim Mustapha Alibe ◽  
Khamirul Amin Matori ◽  
Mohd Hafiz Mohd Zaid ◽  
Salisu Nasir ◽  
Ali Mustapha Alibe ◽  
...  
Keyword(s):  
Solid State ◽  
Thermal Treatment ◽  
Band Gap ◽  
Optical Band Gap ◽  
Dopant Concentration ◽  
Blue Emission ◽  
Green Emission ◽  
Band Gap Energy ◽  
Solid State Lighting ◽  
Gap Energy

The contemporary market needs for enhanced solid–state lighting devices has led to an increased demand for the production of willemite based phosphors using low-cost techniques. In this study, Ce3+ doped willemite nanoparticles were fabricated using polymer thermal treatment method. The special effects of the calcination temperatures and the dopant concentration on the structural and optical properties of the material were thoroughly studied. The XRD analysis of the samples treated at 900 °C revealed the development and or materialization of the willemite phase. The increase in the dopant concentration causes an expansion of the lattice owing to the replacement of larger Ce3+ ions for smaller Zn2+ ions. Based on the FESEM and TEM micrographs, the nanoparticles size increases with the increase in the cerium ions. The mean particles sizes were estimated to be 23.61 nm at 1 mol% to 34.02 nm at 5 mol% of the cerium dopant. The optical band gap energy of the doped samples formed at 900 °C decreased precisely by 0.21 eV (i.e., 5.21 to 5.00 eV). The PL analysis of the doped samples exhibits a strong emission at 400 nm which is ascribed to the transition of an electron from localized Ce2f state to the valence band of O2p. The energy level of the Ce3+ ions affects the willemite crystal lattice, thus causing a decrease in the intensity of the green emission at 530 nm and the blue emission at 485 nm. The wide optical band gap energy of the willemite produced is expected to pave the way for exciting innovations in solid–state lighting applications.

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