Superprotonic conductivity of a 3D anionic metal-organic framework by synergistic effect of guest [Me2NH2]+ cations, water molecules and host carboxylates

2021 ◽  
Vol 299 ◽  
pp. 122168
Author(s):  
Xue-Jian Si ◽  
Jing Jia ◽  
Yu-Liang Bao ◽  
Ya-Pan Wu ◽  
Yunling Liu ◽  
...  
Keyword(s):  
Synergistic Effect ◽  
Metal Organic Framework ◽  
Water Molecules ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Facile Proton Conduction via Ordered Water Molecules in a Phosphonate Metal−Organic Framework

2010 ◽  
Vol 132 (40) ◽  
pp. 14055-14057 ◽  
Author(s):  
Jared M. Taylor ◽  
Roger K. Mah ◽  
Igor L. Moudrakovski ◽  
Christopher I. Ratcliffe ◽  
Ramanathan Vaidhyanathan ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Proton Conduction ◽  
Water Molecules ◽  
Metal Organic ◽  
Ordered Water ◽  
Organic Framework

Intrinsic low dielectric behaviour of a highly thermally stable Sr-based metal–organic framework for interlayer dielectric materials

2014 ◽  
Vol 2 (19) ◽  
pp. 3762-3768 ◽  
Author(s):  
Muhammad Usman ◽  
Cheng-Hua Lee ◽  
Dung-Shing Hung ◽  
Shang-Fan Lee ◽  
Chih-Chieh Wang ◽  
...  
Keyword(s):  
Dielectric Constant ◽  
Metal Organic Framework ◽  
Dielectric Materials ◽  
Low Dielectric Constant ◽  
Water Molecules ◽  
Compound A ◽  
Interlayer Dielectric ◽  
Low Dielectric ◽  
Metal Organic ◽  
Organic Framework

A Sr-based metal–organic framework exhibits an intrinsic low dielectric constant after removing the water molecules. A low dielectric constant and high thermal stability make this compound a candidate for use as a low-k material.

A metal–organic framework with in situ generated low-coordinate binuclear Cu(i) units as a highly effective catalyst for photodriven hydrogen production

2020 ◽  
Vol 56 (49) ◽  
pp. 6700-6703
Author(s):  
Ning-Yu Huang ◽  
Hai He ◽  
Hao Li ◽  
Pei-Qin Liao ◽  
Xiao-Ming Chen
Keyword(s):  
Catalytic Activity ◽  
Hydrogen Production ◽  
Synergistic Effect ◽  
Metal Organic Framework ◽  
High Catalytic Activity ◽  
Binuclear Copper ◽  
Metal Organic ◽  
Cu Ions ◽  
Organic Framework

Here, we report a metal–organic framework featuring a binuclear copper unit, showing extraordinarily high catalytic activity (102.8 mmol g−1 h−1) for photodriven H2 generation, which is attributed to the synergistic effect between the two Cu ions.

Precise regulating synergistic effect in metal–organic framework for stepwise-controlled adsorption

2021 ◽  
Author(s):  
Jiaxing Zhu ◽  
Yi Yu ◽  
Hongchuan Fan ◽  
Huaqiang Cai ◽  
Zhenxia Chen ◽  
...  
Keyword(s):  
Synergistic Effect ◽  
Shape Change ◽  
Metal Organic Framework ◽  
Pore Shape ◽  
Metal Organic ◽  
Controlled Adsorption ◽  
Dyes Mixture ◽  
Organic Framework

MAC-20 shows a unique two-step pore-shape change and executes a stepwise-controlled adsorption of dyes mixture in order of their sizes.

Exploring the multifunctionality in metal–organic framework materials: how do the stilbenedicarboxylate and imidazolyl ligands tune the characteristics of coordination polymers?

2018 ◽  
Vol 42 (8) ◽  
pp. 6408-6415 ◽  
Author(s):  
Marina O. Barsukova ◽  
Sergey A. Sapchenko ◽  
Konstantin A. Kovalenko ◽  
Denis G. Samsonenko ◽  
Andrei S. Potapov ◽  
...  
Keyword(s):  
Synergistic Effect ◽  
Coordination Polymers ◽  
Metal Organic Framework ◽  
Luminescence Properties ◽  
Iodine Vapor ◽  
Framework Materials ◽  
Metal Organic ◽  
Organic Framework

A synergistic effect causes MOF materials to demonstrate excellent iodine vapor retention and luminescence properties.

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