Synthesis, structure, and nonlinear optical property of Bi0.33Sb0.67SI

Three new metal borates, namely K0.5[B6O10]·H2O·1.5H3O (1), [GaB5O10]·H2en (2) and NaCs[Ga{B5O9(OH)}{BO(OH)2}] (3) have been synthesized under solvothermal conditions. Compound 1 features an intricate 3D framework composed of [B6O13]8– clusters, resulting...

Download Full-text

Tunable Nonlinear Optical Property of MnS Nanoparticles with Different Size and Crystal Form

Nanomaterials ◽

10.3390/nano10010034 ◽

2019 ◽

Vol 10 (1) ◽

pp. 34

Author(s):

Zhihao Zhang ◽

Pengchao Li ◽

Yuzong Gu

Keyword(s):

Optical Property ◽

Nonlinear Optical ◽

Nonlinear Optical Property ◽

Nonlinear Refraction ◽

Synthesis Method ◽

Crystal Form ◽

Optical Nonlinearity ◽

Photon Absorption ◽

Third Order ◽

Crystal Forms

It is significant to study the reason that semiconductor material has adjustable third-order optical nonlinearity through crystal form and dimensions are changed. αMnS nanoparticles with different crystal forms and sizes were successfully prepared by one-step hydrothermal synthesis method and their size-limited third-order nonlinear optical property was tested by Z-scan technique with 30 ps laser pulses at 532 nm wavelength. Nanoparticles of different crystal forms exhibited different NLO (nonlinear optical) responses. γMnS had stronger NLO response than αMnS because of higher fluorescence quantum yield. Two-photon absorption and the nonlinear refraction are enhanced as size of nanoparticlesreduced. The nanoparticles had maximum NLO susceptibility which was 3.09 × 10−12 esu. Susceptibility of αMnS increased about nine times than that of largest nanoparticles. However, it was reduced when size was further decreased. This trend was explained by the effects of light induced dipole moments. And defects in αMnS nanoparticles also had effect on this nonlinear process. MnS nanoparticles had potential application value in optical limiting and optical modulation.

Download Full-text

Synthesis, crystal structure and nonlinear optical property of a Zinc(II) complex base on the reduced Schiff-base ligand

Inorganic Chemistry Communications ◽

10.1016/j.inoche.2012.05.026 ◽

2012 ◽

Vol 22 ◽

pp. 82-84 ◽

Cited By ~ 13

Author(s):

Shao-Ming Ying

Keyword(s):

Crystal Structure ◽

Schiff Base ◽

Optical Property ◽

Schiff Base Ligand ◽

Nonlinear Optical ◽

Nonlinear Optical Property ◽

Reduced Schiff Base

Download Full-text

The Preparation and Characterization of Novel Nonlinear Optical Active Dye

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.750-752.899 ◽

2013 ◽

Vol 750-752 ◽

pp. 899-902

Author(s):

Lin Feng Li ◽

Hong Yao Xu

Keyword(s):

Optical Properties ◽

Optical Property ◽

Nonlinear Optical ◽

Nonlinear Optical Property ◽

Condensation Reaction ◽

Nonlinear Optical Properties ◽

532 Nm ◽

Triazine Dye

A novel nonlinear optical active triazine dye 2-(4-methyl-4-amino-azobenzene )-4-sodium sulfanilate-6-chloro-1,3,5-triazine was synthesized by condensation reaction and characterized by FTIR, 1HNMR, respectively. Their nonlinear optical properties were investigated using 5 ns pulse at 532 nm, which showed excellent nonlinear optical property.

Download Full-text