New insights of the peritectic phase transition in steel through in-situ measurement of thermal response in a high-temperature confocal microscope

2020 ◽  
pp. 110841
Author(s):  
Suk-Chun Moon ◽  
Dominic Phelan ◽  
Rian Dippenaar
Keyword(s):  
Phase Transition ◽  
High Temperature ◽  
Thermal Response ◽  
Confocal Microscope ◽  
In Situ Measurement

scholarly journals Development of EXAFS Apparatus for in-situ Measurement of High-Temperature Molten Materials.

1993 ◽  
Vol 32 (6) ◽  
pp. 444-446
Author(s):  
Kazuhiko Omote ◽  
Atsunori Kiku ◽  
Manabu Funahashi ◽  
Kazuyuki Tohji ◽  
Yoshio Waseda
Keyword(s):  
High Temperature ◽  
In Situ Measurement ◽  
Molten Materials

Mn-Mg disordering in cummingtonite: a high-temperature neutron powder diffraction study

2000 ◽  
Vol 64 (2) ◽  
pp. 255-266 ◽  
Author(s):  
J. J. Reece ◽  
S. A. T. Redfern ◽  
M. D. Welch ◽  
C. M. B. Henderson
Keyword(s):  
Crystal Structure ◽  
Phase Transition ◽  
New York ◽  
High Temperature ◽  
Powder Diffraction ◽  
Elevated Temperatures ◽  
Neutron Powder Diffraction ◽  
Site Preference ◽  
A Site

AbstractThe crystal structure of a manganoan cummingtonite, composition [M4](Na0.13Ca0.41Mg0.46Mn1.00) [M1,2,3](Mg4.87Mn0.13)(Si8O22)(OH)2, (Z = 2), a = 9.5539(2) Å, b = 18.0293(3) Å, c = 5.2999(1) Å, β = 102.614(2)° from Talcville, New York, has been refined at high temperature using in situ neutron powder diffraction. The P21/m to C2/m phase transition, observed as spontaneous strains +ε1 = −ε2, occurs at ˜107°C. Long-range disordering between Mg2+ and Mn2+ on the M(4) and M(2) sites occurs above 550°C. Mn2+ occupies the M(4) and M(2) sites preferring M(4) with a site-preference energy of 24.6±1.5 kJ mol−1. Disordering induces an increase in XMnM2 and decrease in XMnM4 at elevated temperatures. Upon cooling, the ordered states of cation occupancy are ‘frozen in’ and strains in lattice parameters are maintained, suggesting that re-equilibration during cooling has not taken place.

Sign in / Sign up

Export Citation Format

Share Document