Green approach to corrosion inhibition of mild steel in two acidic solutions by the extract of Punica granatum peel and main constituents

2012 ◽  
Vol 131 (3) ◽  
pp. 621-633 ◽  
Author(s):  
M. Behpour ◽  
S.M. Ghoreishi ◽  
M. Khayatkashani ◽  
N. Soltani
2019 ◽  
Vol 233 (11) ◽  
pp. 1553-1569 ◽  
Author(s):  
Rola N. Tabesh ◽  
Ashraf Moustafa Abdel-Gaber ◽  
Hassan H. Hammud ◽  
Rami Al-Oweini

Abstract The ligands 1,10-phenanthroline, (P) and para-aminobenzoate, (B); as well as their corresponding MnPB complex [bis-(dimanganese di-μ-paraaminobenzoate dichloro diphenanthroline)] have been investigated as inhibitors of mild steel corrosion in H2SO4 (0.5 M) solutions via potentiodynamic and electrochemical impedance spectroscopy techniques. Stability of the prepared complex was examined by UV-visible spectroscopy. The corrosion inhibition, thermodynamics, and adsorptive properties obtained have shown that MnPB complex has remarkable effects in the acidic solutions. Theoretical fitting of different adsorption isotherms such as Langmuir, Flory–Huggins, and the kinetic-thermodynamic models were tested and the thermodynamic activation parameters were calculated. The data revealed that the corrosion inhibition mechanism of mild steel in acidic solutions by the MnPB complex goes via physicochemical adsorption.


2010 ◽  
Vol 7 (4) ◽  
pp. 1230-1237
Author(s):  
Abha Goyal ◽  
V. K. Swami ◽  
S. P. Mathur

Mass loss techniques have been employed to study the corrosion inhibition of some newly synthesized Schiff bases.viz.N-4-(Diethyl amino) salicylidine-2-amino-5-chloropyridine (SB1),N-(4-ethylbenzalidine)-2-amino-5-chloropyridine (SB2),N-(4-ethylbenzalidine)-2-amino-5-bromopyridine (SB3),N-4-(Diethyl amino) salicylidine-2-amino-5-bromopyridine (SB4) for mild steel in HCl and H2SO4solutions. Results of inhibition efficiencies from the mass loss technique show that Schiff bases are good inhibitors in both the acidic solutions. Inhibition efficiencies increase with the increase in the concentration of acids as well as those of inhibitors. Maximum efficiency for H2SO4was found 99.78% and for HCl it was 97.92%.


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