Patterning of Au nanoparticles via secondary phase-separation of large-sized compound micelles of amphiphilic block copolymer

2017 ◽  
Vol 194 ◽  
pp. 135-137
Author(s):  
Zhida Wang ◽  
Changqing Guo ◽  
Yuan Gan ◽  
Changfeng Yan
2021 ◽  
Author(s):  
Maciej Łojkowski ◽  
Adrian Chlanda ◽  
Emilia Choińska ◽  
Wojciech Swieszkowski

<p>The formation of complex structures in thin films is of interest in many fields. Segregation of polymer chains of different molecular weights is a well-known process. However, here, polystyrene with bimodal molecular weight distribution, but no additional chemical modification was used. It was proven that at certain conditions, the phase separation occurred between two fractions of bimodal polystyrene/methyl ethyl ketone solution. The films were prepared by spin-coating, and the segregation between polystyrene phases was investigated by force spectroscopy. Next, water vapour induced secondary phase separation was investigated. The introduction of moist airflow induced the self-assembly of the lower molecular weight into islands and the heavier fraction into a honeycomb. As a result, an easy, fast, and effective method of obtaining island/honeycomb morphologies was demonstrated. The possible mechanisms of the formation of such structures were discussed.</p>


2002 ◽  
Vol 57 (15) ◽  
pp. 2901-2905 ◽  
Author(s):  
Masato Yamamura ◽  
Takatoshi Nishio ◽  
Toshihisa Kajiwara ◽  
Kitaro Adachi

2018 ◽  
Vol 6 (11) ◽  
pp. 13834-13843 ◽  
Author(s):  
Yongtao Wang ◽  
Huige Yang ◽  
Zhihao Chen ◽  
Ning Chen ◽  
Xinchang Pang ◽  
...  

1988 ◽  
Vol 71 (12) ◽  
pp. 1134-1141 ◽  
Author(s):  
MICHAEL S. RANDALL ◽  
JOSEPH H. SIMMONS ◽  
OSAMA H. EL-BAYOUMI

2018 ◽  
Vol 42 (2) ◽  
pp. 1290-1299 ◽  
Author(s):  
Zhen Wang ◽  
Yongtao Tan ◽  
Ying Liu ◽  
Lengyuan Niu ◽  
Lingbin Kong ◽  
...  

Herein, amphiphilic block copolymer-modified film electrodes were fabricated using poly(acrylic acid)-b-poly(acrylonitrile)-b-poly(acrylic acid) as a surface modifier, polyethersulfone as a matrix polymer, and activated carbon as an active substance by the phase separation method to enhance the wettability of the electrodes.


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