Deoxygenation of pyrolysis vapor from palm fruit cake over NiMo/γ-Al2O3 catalyst: Effect of CeO2, TiO2, and ZrO2 additives

2021 ◽  
pp. 111712
Author(s):  
Worada Moonsrikaew ◽  
Apinya Duangchan
2015 ◽  
Vol 27 (4) ◽  
pp. 1293-1298 ◽  
Author(s):  
Ke Zhang ◽  
Haitao Zhang ◽  
Hongfang Ma ◽  
Weiyong Ying ◽  
Dingye Fang

2016 ◽  
Vol 16 (2) ◽  
pp. 1855-1858 ◽  
Author(s):  
Gwang-Sub Go ◽  
Yoo-Jin Go ◽  
Hong-Joo Lee ◽  
Dong-Ju Moon ◽  
Nam-Cook Park ◽  
...  

1989 ◽  
Vol 54 (8) ◽  
pp. 2069-2082 ◽  
Author(s):  
Hana Zahradníková ◽  
Ludvík Beránek

Oxygen chemisorption by pulse dynamic method at room temperature and the activity for ethylene hydrogenation at 300 °C in a flow regime were determined for Co-Mo/Al2O3 catalyst CHEROX 36-01 sulphided by a H2S/H2 (1:10) mixture at 400 °C. The measurements were carried out either immediately after sulphidation or after subsequent reduction of the sulphided catalyst by hydrogen. The chemisorption of oxygen was measured both prior to and after the catalytic reaction. In addition, the reactivation of the catalyst was examined after its passivation by oxygen chemisorption. The reactivation was effected either by resulphidation or by reduction with hydrogen at 400 °C, on repeated reactivation also by combination of both procedures, variables being the time of activation and reactivation steps. The results are discussed from the standpoint of the structure and interrelation between active sites for oxygen chemisorption and catalytic, especially hydrogenation reactions. Formation of coordinately unsaturated sites and SH groups is emphasized. The reasons of possible failures in correlations between chemisorption capacity for oxygen and catalytic activity are mentioned.


Fuel ◽  
2019 ◽  
Vol 235 ◽  
pp. 437-447 ◽  
Author(s):  
K. Kohli ◽  
R. Prajapati ◽  
Samir K. Maity ◽  
M. Sau ◽  
Brajendra K. Sharma

2013 ◽  
Vol 22 (1) ◽  
pp. 27-34 ◽  
Author(s):  
Ahmed E. Awadallah ◽  
Fatma Kh. Gad ◽  
Ateyya A. Aboul-Enein ◽  
Mahmoud R. Labib ◽  
Ahmed K. Aboul-Gheit

Author(s):  
Phathutshedzo Rodney Khangale ◽  
Reinout Meijboom ◽  
Kalala Jalama

The effect of activating Co/Al2O3 catalyst by diluted CO or H2 on catalyst performance for Fischer-Tropsch reaction was investigated. The catalyst was prepared by incipient wetness impregnation of the support and characterized using BET N2 physisorption, SEM, and XRD analyses. The reduction behavior of the catalyst in presence of CO and H2 individually was evaluated using TPR analyses. The data reveal that CO activates Co/Al2O3 catalyst at a lower temperature than H2 and produces a catalyst with higher rate for liquid product formation. It also leads to higher methane selectivity probably due to some cobalt carbide formation. Copyright © 2019 BCREC Group. All rights reservedReceived: 9th April 2018; Revised: 21st August 2018; Accepted: 27th August 2018; Available online: 25th January 2019; Published regularly: April 2019How to Cite: Khangale, P.R., Meijboom, R., Jalama, K. (2019). Fischer-Tropsch Synthesis over Unpromoted Co/ɣ-Al2O3 Catalyst: Effect of Activation with CO Compared to H2 on Catalyst Performance. Bulletin of Chemical Reaction Engineering & Catalysis, 14 (1): 35-41 (doi:10.9767/bcrec.14.1.2519.35-41)Permalink/DOI: https://doi.org/10.9767/bcrec.14.1.2519.35-41 


2009 ◽  
Vol 10 (9) ◽  
pp. 1358-1362 ◽  
Author(s):  
Jong Wook Bae ◽  
Seung-Moon Kim ◽  
Yun-Jo Lee ◽  
Min-Jae Lee ◽  
Ki-Won Jun

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