Nanoparticles of iron and vanadium oxides supported on iron substituted LDHs: Synthesis, textural characterization and their catalytic behavior in ethylbenzene dehydrogenation

2008 ◽  
Vol 115 (3) ◽  
pp. 541-547 ◽  
Author(s):  
Gabriela Carja ◽  
Yoshikazu Kameshima ◽  
Kiyoshi Okada
2005 ◽  
Vol 288 (1-2) ◽  
pp. 220-231 ◽  
Author(s):  
Yoshihiko Ohishi ◽  
Tomonori Kawabata ◽  
Tetsuya Shishido ◽  
Ken Takaki ◽  
Qinghong Zhang ◽  
...  

2018 ◽  
Author(s):  
Katie O'Sullivan ◽  
◽  
Stewart Harvin ◽  
Virginia Rodriguez ◽  
Favour Epuna ◽  
...  

2017 ◽  
Vol 2 (20) ◽  
pp. 5800-5804 ◽  
Author(s):  
Marie Guignard ◽  
Claude Delmas
Keyword(s):  

Materials ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3276
Author(s):  
Aitana Tamayo ◽  
Juan Rubio ◽  
Fausto Rubio ◽  
Mᵃ Angeles Rodriguez

Silicon oxycarbide ceramers containing 5% aluminum, zirconium, and cobalt with respect to the total Si amount are prepared from a commercial polysiloxane and molecular precursors and pyrolyzed at temperatures ranging from 500 to 1000 °C. HF etching is carried out to partially digest the silica phase, thus revealing structural characteristics of the materials, which depend upon the incorporated heteroatom. From the structural and textural characterization, it was deduced that when Al enters into the ceramer structure, the crosslinking degree is increased, leading to lower carbon domain size and carbon incorporation as well. On the contrary, the substitution by Zr induced a phase-separated SiO2-ZrO2 network with some degree of mesoporosity even at high pyrolysis temperatures. Co, however, forms small carbidic crystallites, which strongly modifies the carbonaceous phase in such a way that even when it is added in a small amount and in combination with other heteroatoms, this transient metal dominates the structural characteristics of the ceramer material. This systematic study of the ceramer compounds allows the identification of the ultimate properties of the polymer-derived ceramic composites.


Molbank ◽  
10.3390/m1217 ◽  
2021 ◽  
Vol 2021 (2) ◽  
pp. M1217
Author(s):  
Rebeca González-Fernández ◽  
Pascale Crochet ◽  
Victorio Cadierno

The title compound, i.e., [RuCl2(η6-p-cymene)(PPh2NHnPr)] (2), was obtained in a 71% yield by reacting a toluene solution of the chlorophosphine complex [RuCl2(η6-p-cymene)(PPh2Cl)] (1) with two equivalents of n-propylamine at room temperature. The aminophosphine complex 2 was characterized by elemental analysis, multinuclear NMR (31P{1H}, 1H and 13C{1H}) and IR spectroscopy. In addition, its catalytic behavior in the hydration of benzonitrile was briefly explored.


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