Study on thermodynamics, dynamics and reverse shape separation selectivity of mesoporous UiO-66 for nHEP/MCH

Author(s):  
Zongjian Liu ◽  
Zhicong Sun ◽  
Zhao Zhang ◽  
Lifei Xu ◽  
Lin Zhang ◽  
...  
2019 ◽  
Vol 212 ◽  
pp. 877-886 ◽  
Author(s):  
V. Zhmakin ◽  
M. Shalygin ◽  
V. Khotimskiy ◽  
S. Matson ◽  
V. Teplyakov

2012 ◽  
Vol 608-609 ◽  
pp. 1337-1341
Author(s):  
Hong Liang Chen ◽  
Ji Song Yang ◽  
Yan Wang ◽  
Hui Ying Li ◽  
Xin Xin Li ◽  
...  

Silicalite-1 membranes were successfully synthesized on α-Al2O3 tubes by in-situ hydrothermal synthesis after filling the tubes with water and glycerol mixtures, and all the membranes show high concentration performance towards ethanol/water mixtures after pretreating tubes with different NaOH solution. The results show that the flux enhances with the enhancement of NaOH solution concentration, but the separation selectivity decreases with the enhancement of NaOH solution concentration. After pretreating the α-Al2O3 tubes with different NaOH solution, the weight of all the α-Al2O3 tube decreases, but the Si/Al ratio increases, which shows that suitable pretreatment of α-Al2O3 is useful for improving the hydrophobicity of silicalite-1 membranes.


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