Comparative study of electrochemical oxidation and electrochemical Fenton processes for simultaneous degradation of phthalic and para-toluic acids from aqueous medium

2017 ◽  
Vol 243 ◽  
pp. 519-532 ◽  
Author(s):  
Vishal Kumar Sandhwar ◽  
Basheshwar Prasad
Carbon ◽  
1993 ◽  
Vol 31 (1) ◽  
pp. 223-226 ◽  
Author(s):  
H. Shioyama ◽  
M. Crespin ◽  
A. Seron ◽  
R. Setton ◽  
D. Bonnin ◽  
...  

2017 ◽  
Vol 326 ◽  
pp. 811-819 ◽  
Author(s):  
Carlota Ridruejo ◽  
Claudio Salazar ◽  
Pere L. Cabot ◽  
Francesc Centellas ◽  
Enric Brillas ◽  
...  

2020 ◽  
Vol 10 (6) ◽  
pp. 2091 ◽  
Author(s):  
Zuzana Morávková ◽  
Ivana Šeděnková ◽  
Patrycja Bober

There are several types of aniline oligomers that can be formed in the early stages of aniline oxidation: linear oligomers with repeating units joined in para positions, and various branched and polycyclic oligomers, being the two most important groups. The fraction of these different oligomeric groups depends upon the reaction conditions of aniline oxidation. The aim of this study was to analyze the first products of the chemical and electrochemical oxidation of aniline at the (starting) pH 1 and 7, in order to specify the conditions of the formation of phenazine-like oligomers, and to test the theory that they have an important role in polyaniline film formation. We have confirmed that phenazine-like oligomers do not form at pH 1, neither in the chemical nor the electrochemical oxidation of aniline; however, they form in both chemical and electrochemical oxidation of aniline at pH 7. Phenazine-like oligomers are thus definitely not necessary intermediates for PANI film formation, not even in the chemical polymerization of aniline. Finally, the redox behavior of phenazine-like oligomers was demonstrated in a medium at pH 1.


2007 ◽  
Vol 37 (9) ◽  
pp. 985-990 ◽  
Author(s):  
G. R. Agladze ◽  
G. S. Tsurtsumia ◽  
B. -I. Jung ◽  
J. -S. Kim ◽  
G. Gorelishvili

Chemosphere ◽  
2012 ◽  
Vol 88 (2) ◽  
pp. 155-160 ◽  
Author(s):  
S.A. Alves ◽  
T.C.R. Ferreira ◽  
N.S. Sabatini ◽  
A.C.A. Trientini ◽  
F.L. Migliorini ◽  
...  

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