Water confined (H2O) n=1–10 amino acid-based ionic liquids – A DFT study on the bonding, energetics and IR spectra

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Senthilkumar Lakshmipathi
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Hongyan He

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Yutong Wang ◽  
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J.E. Castellanos-Águila ◽  
H. HernÁndez-Cocoletzi ◽  
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M. Trejo-Durán ◽  
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Giancarlo Masci ◽  
Francesco Casciotta ◽  
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Fourteen cholinium-amino acid based room temperature ionic liquids were prepared using a cleaner synthetic method. Chemicophysical properties were well correlated with the wide range of amino acid chemical structures.


Author(s):  
Andrea Le Donne ◽  
Enrico Bodo

AbstractBoosted by the simplicity of their synthesis and low toxicity, cholinium and amino acid-based ionic liquids have attracted the attention of researchers in many different fields ranging from computational chemistry to electrochemistry and medicine. Among the uncountable IL variations, these substances occupy a space on their own due to their exceptional biocompatibility that stems from being entirely made by metabolic molecular components. These substances have undergone a rather intensive research activity because of the possibility of using them as greener replacements for traditional ionic liquids. We present here a short review in the attempt to provide a compendium of the state-of-the-art scientific research about this special class of ionic liquids based on the combination of amino acid anions and cholinium cations.


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