scholarly journals Cholinium amino acid-based ionic liquids

Author(s):  
Andrea Le Donne ◽  
Enrico Bodo

AbstractBoosted by the simplicity of their synthesis and low toxicity, cholinium and amino acid-based ionic liquids have attracted the attention of researchers in many different fields ranging from computational chemistry to electrochemistry and medicine. Among the uncountable IL variations, these substances occupy a space on their own due to their exceptional biocompatibility that stems from being entirely made by metabolic molecular components. These substances have undergone a rather intensive research activity because of the possibility of using them as greener replacements for traditional ionic liquids. We present here a short review in the attempt to provide a compendium of the state-of-the-art scientific research about this special class of ionic liquids based on the combination of amino acid anions and cholinium cations.

2021 ◽  
Vol 287 ◽  
pp. 02018
Author(s):  
Nur Khairunnisa Talib ◽  
Omar Nashed ◽  
Bhajan Lal ◽  
Ouahid Ben Ghanem

Ionic liquids are promising materials for several applications. Amino acid based ionic liquids (AAILs) as a sort of a new generation of ionic liquids are recently proposed taking advantage of hydrogen bonding group and low toxicity. Three types of AAILs are examined in this work; namely 1-Octyl-3-Methylimidazolium Glycine [OMIM][Gly], 1-Octyl-3-Methylimidazolium Alanine [OMIM][Ala] and 1-Octyl-3-Methylimidazolium Proline [OMIM][Pro]. The pH and molar conductivity are measured at ambient conditions for AAILs aqueous solutions at different concentrations; specifically 1, 10, 20, and 30 wt.%. The experimental results show that all AAILs solutions are alkaline (pH>7) where [OMIM][Pro] has the highest pH compared to its counterparts. The trend is reversed for molar conductivity as [OMIM][Gly] showed the highest molar conductivity. These results are attributed to the smaller size of [Gly] compared to [Pro] and [Ala]. However, adding AAILs increases the molar conductivity of the water.


2021 ◽  
Author(s):  
Yusuke Minami ◽  
Yutaka Amao

Formate is attracting attention as a hydrogen carrier because of its low toxicity and easy handling in aqueous solution. In order to utilize formic acid as a hydrogen carrier, a...


2015 ◽  
Vol 17 (32) ◽  
pp. 20687-20698 ◽  
Author(s):  
Serena De Santis ◽  
Giancarlo Masci ◽  
Francesco Casciotta ◽  
Ruggero Caminiti ◽  
Eleonora Scarpellini ◽  
...  

Fourteen cholinium-amino acid based room temperature ionic liquids were prepared using a cleaner synthetic method. Chemicophysical properties were well correlated with the wide range of amino acid chemical structures.


2021 ◽  
Author(s):  
Zenghui Wang ◽  
Pingping Zhao ◽  
Jimin Wu ◽  
Jun Gao ◽  
Lianzheng Zhang ◽  
...  

The design of stable ionic liquids (ILs) has become crucial for efficient liquid-liquid extraction (LLE) of alcohol and water. Porous ionic liquids (PILs), as a special class of ILs, have...


ChemSusChem ◽  
2016 ◽  
Vol 9 (8) ◽  
pp. 763-763
Author(s):  
Qiwei Yang ◽  
Zhiping Wang ◽  
Zongbi Bao ◽  
Zhiguo Zhang ◽  
Yiwen Yang ◽  
...  

2008 ◽  
Vol 24 (1) ◽  
pp. 225-230 ◽  
Author(s):  
Liza S. Comita ◽  
Gregory R. Goldsmith ◽  
Stephen P. Hubbell

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