One- and two-dimensional divalent copper coordination polymers based on kinked organodiimine and long flexible aliphatic dicarboxylate ligands

2008 ◽  
Vol 891 (1-3) ◽  
pp. 423-428 ◽  
Author(s):  
Subhashree Mallika Krishnan ◽  
Ronald M. Supkowski ◽  
Robert L. LaDuca
Keyword(s):  
Coordination Polymers ◽  
Two Dimensional ◽  
Divalent Copper ◽  
Copper Coordination

Synthesis and Magnetic Properties of Dual-Ligand Divalent Copper Coordination Polymers with Rhomboid Layer, Archimedean Grid, and Self-Penetrated Network Topologies

2010 ◽  
Vol 10 (1) ◽  
pp. 335-343 ◽  
Author(s):  
Laura K. Sposato ◽  
Joseph H. Nettleman ◽  
Maxwell A. Braverman ◽  
Ronald M. Supkowski ◽  
Robert L. LaDuca
Keyword(s):  
Magnetic Properties ◽  
Coordination Polymers ◽  
Divalent Copper ◽  
Copper Coordination ◽  
Network Topologies

Two-dimensional lanthanide(III) coordination polymers: solvothermal synthesis, crystal structure, and stability

2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Runmei Ding ◽  
Zixin He ◽  
Meilin Wang ◽  
Danian Tian ◽  
Peipei Cen
Keyword(s):  
Crystal Structure ◽  
Coordination Polymers ◽  
Solvothermal Synthesis ◽  
Analysis Data ◽  
Water Stability ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
Triclinic Space Group ◽  
X Ray ◽  
Solvothermal Conditions

AbstractBased on 2-(4-pyridyl)-terephthalate (H2pta) and oxalate ligands, two new lanthanide-containing coordination polymers (CPs), [Tb(pta)(C2O4)0.5(H2O)2)]·2H2O (1) and [Sm(pta)(C2O4)0.5(H2O)2)]·2H2O (2), have been synthesized under solvothermal conditions. The structures of both 1 and 2 have been determined by single-crystal X-ray diffraction. Infrared, elemental analysis, powder X-ray diffraction and thermogravimetric analysis data are also presented. The crystals of 1 and 2 exhibit isostructural layer-like networks, crystallizing in the triclinic space group P$‾{1}$. The layers are further stabilized and associated into 3D architectures through hydrogen bonding. Remarkably, the CPs 1 and 2 exhibit excellent water stability and remarkable thermostability with thermal decomposition temperatures of more than 420 °C.

Sign in / Sign up

Export Citation Format

Share Document