Synthesis, complexation studies and structural characterization of d and f metal ion complexes with 4-chloroquinaldinic acid N-oxide

Abstract The structural characterization of the newly synthesized trinitrato(terpyridine)lanthanoid complexes [Nd(NO3)3(pytpy)(H2O)] (1), [Eu(NO3)3(pytpy)(EtOH)]·EtOH (2·EtOH) and [Tb(NO3)3(ptpy)(EtOH)] (3), with the modified terpyridine ligands pytpy = 4′-(pyridin-3-yl)-2,2′:6′,2″-terpyridine and ptpy = 4′-phenyl-2,2′:6′,2″-terpyridine, show all a coordination number of 10 at the metal ion with three bidentate nitrato ligands and an additional solvent ligand. The coordination polyhedra around the metal ions are highly irregular. Hirshfeld surface analyses of the intermolecular interactions show (C/O–)H⋯O bonding having the largest percentage contribution in all three structures, while there are remarkably few π-π interactions despite the numerous aryl rings.

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Synthesis and structural characterization of bisazocalix[4]arene with melamine: Metal ion extraction studies

Journal of Molecular Liquids ◽

10.1016/j.molliq.2014.12.020 ◽

2015 ◽

Vol 202 ◽

pp. 134-140 ◽

Cited By ~ 4

Author(s):

Serkan Elçin ◽

Özlem Özen Karakuş ◽

İzzet Kara ◽

Hasalettin Deligöz

Keyword(s):

Structural Characterization ◽

Metal Ion ◽

Metal Ion Extraction ◽

Ion Extraction

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Metal-ion-binding properties of ulvan extracted from Ulva clathrata and structural characterization of its complexes

Carbohydrate Polymers ◽

10.1016/j.carbpol.2021.118508 ◽

2021 ◽

pp. 118508

Author(s):

Yongzhou Chi ◽

Huini Li ◽

Li Fan ◽

Chunying Du ◽

Jingliang Zhang ◽

...

Keyword(s):

Structural Characterization ◽

Metal Ion ◽

Ion Binding ◽

Metal Ion Binding ◽

Binding Properties ◽

Ulva Clathrata

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Metal Ion Binding to Calixarenes: Pendent Arm Coordination Assisted by Self-Inclusion

Australian Journal of Chemistry ◽

10.1071/ch9941185 ◽

1994 ◽

Vol 47 (6) ◽

pp. 1185 ◽

Cited By ~ 8

Author(s):

JM Harrowfield ◽

M Mocerino ◽

BW Skelton ◽

CR Whitaker ◽

AH White

Keyword(s):

Structural Characterization ◽

Metal Ion ◽

Room Temperature ◽

Ion Binding ◽

Metal Ion Binding ◽

Cone Conformation ◽

X Ray ◽

Partial Cone ◽

Arm Coordination

The synthesis and room-temperature single-crystal X-ray structural characterization of 25,27- di(allyloxy)-5,17-di-t-butyl-26,28-dimethoxycalix[4]arene are recorded. Crystals are monoclinic, C2/c, a 29.089(5), b 10.742(2), c 26.218(8) Ǻ, β 110.09(2)°, Z = 8; the structure was refined to a residual of 0.065 for 4103 independent 'observed' [I > 3σ(I)] reflections. The flattened partial cone conformation of the molecule allows inclusion of one of the methoxy substituents in a way which could block inclusion of a metal ion capable of polyhapto aromatic coordination and which may therefore explain why solution n.m.r. measurements indicate that silver(I) binds to the pendent alkene groups.

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