Synthesis, molecular and solid state structure of 5-(5-nitro furan-2-ylmethylen), 3- N -(2-methoxy phenyl), 2- N ′-(2-methoxyphenyl) imino thiazolidin-4-one: X-ray powder diffraction and DFT studies

The reduction of magnesium phthalocyanine (MgPc) with 2.2 equivalents of potassium graphite in 1,2-dimethoxyethane (DME) gives [K2(DME)4]PcMg(OH)(1) in 67% yield. Compound 1 was structurally characterized using single crystal X-ray crystallography and was found to be a monomeric, heterometallic complex consisting of a μ3-OH ligand that bridges a [MgIIPc3-]- anion to two potassium cations solvated by four DME molecules. An absorption spectrum of 1 confirms the Pc ligand is singly reduced and has a 3–charge. The solid-state structure of 1 does not indicate breaking of the aromaticity of the Pc ligand. Compound 1 is only the second Pc3- complex and the first reduced MgPc to be isolated and structurally characterized.

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Solid-state structure and solution conformation of 2,2,4,4,6,6,-hexa-(p-chlorophenoxo)cyclotri-λ5-phosphazatriene. X-Ray and dipole moment studies

Journal of the Chemical Society Dalton Transactions ◽

10.1039/dt9890000757 ◽

1989 ◽

pp. 757-760 ◽

Cited By ~ 11

Author(s):

Giuliano Bandoli ◽

Umberto Casellato ◽

Mario Gleria ◽

Antonio Grassi ◽

Enzo Montoneri ◽

...

Keyword(s):

Dipole Moment ◽

Solid State ◽

State Structure ◽

Solution Conformation ◽

Solid State Structure ◽

X Ray

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Structural Study of an Acyclic Diterpene From Eremophila Species

Australian Journal of Chemistry ◽

10.1071/ch9960701 ◽

1996 ◽

Vol 49 (6) ◽

pp. 701 ◽

Cited By ~ 1

Author(s):

YM Syah ◽

EL Ghisalberti ◽

BW Skelton ◽

AH White

Keyword(s):

Solid State ◽

Single Crystal ◽

Structural Study ◽

Room Temperature ◽

State Structure ◽

Solid State Structure ◽

X Ray

The solid-state structure of the semicarbazone derivative (3) of the aldehyde diacid (1), an acyclic diterpene isolated from Eremophila species, has been determined by a single-crystal room-temperature X-ray study. Crystals of (3) are triclinic, Pī , a 14.642(7), b 14.371(6), c 12.823(6) Ǻ, α 76.59(4), β 66.09(4), γ 72.97(4)°, Z = 4; R was 0.052 for 2265 independent 'observed' (I > 3σ(I)) diffractometer reflections.

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N–O Bond Cleavage During the Deprotonation of N,O-Bis(trimethylsilyl)hydroxylamine

Zeitschrift für Naturforschung B ◽

10.1515/znb-2008-0319 ◽

2008 ◽

Vol 63 (3) ◽

pp. 339-341 ◽

Cited By ~ 5

Author(s):

Ajay Venugopal ◽

Alexander Willner ◽

Norbert W. Mitzel

Keyword(s):

Solid State ◽

Single Crystal ◽

Elemental Analysis ◽

Bond Cleavage ◽

State Structure ◽

X Ray Diffraction ◽

Solid State Structure ◽

X Ray ◽

Potassium Hydride ◽

Oxygen Atoms

The reaction of N,O-bis(trimethylsilyl)hydroxylamine with potassium hydride in pentane affords a product of the formula {K6[OSiMe3]4[ON(SiMe3)2]2}, resulting from deprotonation followed by N-O bond cleavage and 1,2-silylshift. The compound was characterised by elemental analysis and by single crystal X-ray diffraction. The aggregate consists of a K3O3 bis-cubane core, with N(SiMe3)2 groups at the oxygen atoms shared by the two cubes, andMe3Si groups attached to the four O vertices. Two weak K···N interactions are also detected in the solid state structure.

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Notizen: Solid State Structure of N,N-Dibenzylhydroxylamine

Zeitschrift für Naturforschung B ◽

10.1515/znb-1995-0441 ◽

1995 ◽

Vol 50 (4) ◽

pp. 699-701 ◽

Cited By ~ 1

Author(s):

Norbert W. Mitzel ◽

Jürgen Riede ◽

Klaus Angermaier ◽

Hubert Schmidbaur

Keyword(s):

Solid State ◽

Hydrogen Bonds ◽

Single Crystal ◽

Unit Cell ◽

Monoclinic Space Group ◽

State Structure ◽

X Ray Diffraction ◽

Space Group ◽

Solid State Structure ◽

X Ray

The solid-state structure of N,N-dibenzylhydroxylamine (1) has been determined by single crystal X-ray diffraction. The compound crystallizes in the monoclinic space group P 21/n with four formula units in the unit cell. N,N-dibenzylhydroxylamine dimerizes to give N2O2H2 sixmembered rings as a result of the formation of two hydrogen bonds O - H ··· N in the solid state.

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