Grain boundary plasticity in solid solution Mg–Li binary alloy

2020 ◽  
Vol 790 ◽  
pp. 139705 ◽  
Author(s):  
Hidetoshi Somekawa ◽  
Daisuke Egusa ◽  
Eiji Abe
1985 ◽  
Vol 49 (353) ◽  
pp. 547-554 ◽  
Author(s):  
M. Shahmiri ◽  
S. Murphy ◽  
D. J. Vaughan

AbstractThe crystal structure and compositional limits of the ternary compound Pt2FeCu (tulameenite), formed either by quenching from above the critical temperature of 1178°C or by slow cooling, have been investigated using X-ray diffraction, transmission electron microscopy, differential thermal analysis and electron probe microanalysis.The crystal structure of Pt2FeCu, established using electron density maps constructed from the measured and calculated intensities of X-ray diffraction patterns of powdered specimens, has the (000) and (½½0) lattice sites occupied by Pt atoms and the (½0½) and (0½½) sites occupied by either Cu or Fe atoms in a random manner. The resulting face-centred tetragonal structure undergoes a disordering transformation at the critical temperature to a postulated non-quenchable face-centred cubic structure. Stresses on quenching, arising from the ordering reaction, are relieved by twinning along {101} planes or by recrystallization along with deformation twinning; always involving grain boundary fracturing.Phase relations in the system Pt-Fe-Cu have been investigated through the construction of isothermal sections at 1000 and 600°C. At 1000°C there is an extensive single phase region of solid solution around Pt2FeCu and extending to the binary composition PtFe. At 600°C the composition Pt2FeCu lies just outside this now reduced area of solid solution in a two-phase field. Comparison of the experimental results with data for tulameenite suggests that some observed compositions may be metastably preserved. The occurrence of fine veinlets of silicate or other gangue minerals in tulameenite is suggested to result from grain boundary fracturing on cooling below the critical temperature of 1178°C and to be evidence of a magmatic origin.


1979 ◽  
Vol 27 (12) ◽  
pp. 1849-1854 ◽  
Author(s):  
B. Aufray ◽  
F. Cabane-Brouty ◽  
J. Cabane

2011 ◽  
Vol 335-336 ◽  
pp. 615-618
Author(s):  
Hong Mei Zhang ◽  
Li Feng Qiao

The cold rolling and simulative continuous annealing experiments after rolling were carried out in the laboratory on the base of super fine grain (SFG) steel sheet. The microstructure and the second-phase particles precipitated behavior were analyzed by the technology of OM, TEM and EDX. It is found that the fined Nb(C, N) can be formed by adding micro-alloy element Nb. It is noted that the yield strength is low as well as the tensile strength is high by the PFZ which is free of precipitate called precipitated free zone on the one side of the grain boundary. Contrast to the conventional IF steel, the super fine grain steel has super fine grains and gives excellent press-formability such as low yield strength, high r-value(the plastic strain ratio). High strength cold-rolled steel sheets (HSS) with high formability have been developed in the last decade, in which the major strengthening method was solid-solution hardening with silicon, manganese and phosphorous [1-3]. When the IF steel is strengthened with the high amount of solid-solution elements, it becomes susceptible to the secondary work embrittlement because of the lack of grain boundary strength [4-6]. In this paper, High strength cold-rolled steel sheets (HSS) with high formability have been developed for the IF steel-bases. The grain refinement and precipitation hardening are achieved by means of the fine distribution of carbide under the appropriate combination of the relatively higher carbon content near 0.0070 mass% with niobium. As the result, this type of IF-HSS has been successfully developed to reach a higher r-value as compared with the conventional IF-HSS.


A technique has been developed for the determination of the absolute surface energies of iron and iron alloys at temperatures of up to the melting point. The technique is based upon the measurement of the contractile forces in thin foils. All measurements are made in situ and chemical equilibrium is maintained throughout the experiment. The results show that phosphorus in dilute solid solution decreases progressively the surface energy of iron at 1450 °C from 2100 ergs cm -2 to 1200 ergs cm -2 , for increasing phosphorus contents of up to 0.36%. Results were also obtained for the γ phase in which the effect is less pronounced. Absolute grain boundary energies were also determined as a function of phosphorus content. From the strain rate of the foils which move by a diffusion creep mechanism, it was deduced that the self diffusion coefficient increases linearly with phosphorus content. Application of the Gibbs adsorption theorem has permitted the evaluation of the extents of equilibrium segregation of the solute to interfaces. The maximum levels are 2.3 x 10 -9 g-atom cm -2 at surfaces and 1.1 x 10 -9 g-atom cm -2 at grain boundaries. The relevance of these measurements to the problem of the intergranular brittle fracture of iron/phosphorus alloys is discussed.


1983 ◽  
Vol 31 (7) ◽  
pp. 1047-1052 ◽  
Author(s):  
A. Pineau ◽  
B. Aufray ◽  
F. Cabane-Brouty ◽  
J. Cabane

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