Efficient near-infrared organic light-emitting diodes based on multimetallic assemblies of lanthanides and iridium complexes

2010 ◽  
Vol 11 (3) ◽  
pp. 369-376 ◽  
Author(s):  
Zhu-Qi Chen ◽  
Fei Ding ◽  
Zu-Qiang Bian ◽  
Chun-Hui Huang
Molecules ◽  
2022 ◽  
Vol 27 (1) ◽  
pp. 286
Author(s):  
Shuonan Chen ◽  
Hai Bi ◽  
Wenjing Tian ◽  
Yu Liu

Six novel Ir(C^N)2(L^X)-type heteroleptic iridium complexes with deep-red and near-infrared region (NIR)-emitting coverage were constructed through the cross matching of various cyclometalating (C^N) and ancillary (LX) ligands. Here, three novel C^N ligands were designed by introducing the electron-withdrawing group CF3 on the ortho (o-), meta (m-), and para (p-) positions of the phenyl ring in the 1-phenylisoquinoline (piq) group, which were combined with two electron-rich LX ligands (dipba and dipg), respectively, leading to subsequent iridium complexes with gradually changing emission colors from deep red (≈660 nm) to NIR (≈700 nm). Moreover, a series of phosphorescent organic light-emitting diodes (PhOLEDs) were fabricated by employing these phosphors as dopant emitters with two doping concentrations, 5% and 10%, respectively. They exhibited efficient electroluminescence (EL) with significantly high EQE values: >15.0% for deep red light0 (λmax = 664 nm) and >4.0% for NIR cases (λmax = 704 nm) at a high luminance level of 100 cd m−2. This work not only provides a promising approach for finely tuning the emission color of red phosphors via the easily accessible molecular design strategy, but also enables the establishment of an effective method for enriching phosphorescent-emitting molecules for practical applications, especially in the deep-red and near-infrared region (NIR).


2018 ◽  
Vol 6 (6) ◽  
pp. 1407-1412 ◽  
Author(s):  
Yun Hu ◽  
Yi Yuan ◽  
Ying-Li Shi ◽  
Jiu-Dong Lin ◽  
Zuo-Quan Jiang ◽  
...  

A maximum EQE of 2.7% with an emission peak of 735 nm was achieved by employing a donor–acceptor type host 5-(4-(diphenylamino)phenyl)acenaphthylene-1,2-dione (ADO-TPA).


Author(s):  
Shuonan Chen ◽  
Xi Gai ◽  
Jie Liang ◽  
Kaiqi Ye ◽  
Yu Liu ◽  
...  

Two new phenylpyridine derivatives-based heteroleptic iridium complexes, (Fppy)2Ir(dipg) (Fppdg) and (CF3ppy)2Ir(dipg) (tFmppdg) with emission peaks of 545 nm and 581 nm respectively, were designed and synthesized by incorporation of a...


Sign in / Sign up

Export Citation Format

Share Document