Synthesis, structural characterisation and thermal decomposition of a new organic–inorganic hybrid material (C5H14N2)[Cu(SO4)2(H2O)4]·H2O

Polyhedron ◽  
2009 ◽  
Vol 28 (11) ◽  
pp. 2113-2118 ◽  
Author(s):  
Fadhel Hajlaoui ◽  
Samia Yahyaoui ◽  
Houcine Naïli ◽  
Tahar Mhiri ◽  
Thierry Bataille
2017 ◽  
Vol 727 ◽  
pp. 272-279 ◽  
Author(s):  
Jing Yang ◽  
Hong Jun Li ◽  
Rui Hua Mu ◽  
Ya Mei Zhao ◽  
Zhi Tong

Pd-doped SiO2 organic-inorganic hybrid material (Pd/M-SiO2) was prepared by sol-gel method and characterized by XRD, FTIR spectra and TG/DTG analysis. The most probable kinetic mechanism function, apparent activation energy and pre-exponential factor of the thermal decomposition for Pd/M-SiO2 material were calculated using the combined Coast-Redfern intergral and Αchar differential methods. Pd element in noncalcined Pd/M-SiO2 materials exists in PdCl2 form. FTIR spectroscopy confirmed the existence of hydrophobic Si−CH3 groups. The thermal decomposition process of Pd/M-SiO2 materials can be divided into four stages, with different mechanism functions. The activation energies are 76.37, 146.85, 208.90 and 413.89 kJ·mol−1 for the four stages, respectively, and the pre-exponential factors are 5.04×1012, 7.14×1013, 2.93×1012 and 6.56×1019 s−1, respectively. There is no obvious influence of the existence of metallic Pd0 on the thermal decomposition of methyl.


2007 ◽  
Vol 36 (3) ◽  
pp. 374-375 ◽  
Author(s):  
Hong-Yu Zeng ◽  
Wei-Min Huang ◽  
Jian-Lin Shi

2021 ◽  
pp. 132012
Author(s):  
Imen Tlili ◽  
Rim Essalhi ◽  
George Mousdi ◽  
Mohammed S.M. Abdelbaky ◽  
Slaheddine Chaabouni

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