Partitioning of the components into two-demixed-macrophases from a solution blend emulating high impact polystyrene close to the phase inversion region

Polymer ◽  
2020 ◽  
Vol 198 ◽  
pp. 122523
Author(s):  
Eliezer Velásquez ◽  
Ilibeth Morales ◽  
María Montero ◽  
Haydée Oliva ◽  
Alejandro J. Müller ◽  
...  
2019 ◽  
Vol 60 (3) ◽  
pp. 491-502 ◽  
Author(s):  
Juan M. Maffi ◽  
Natalia Casis ◽  
Pablo Acuña ◽  
Graciela Morales ◽  
Diana A. Estenoz

2019 ◽  
pp. 20-23
Author(s):  
E. N. Tkacheva ◽  
O. M. Trifonova ◽  
I. G. Akhmetov

The eff ect of butadiene rubber molecular parameters on conversion dependencies and viscosity characteristics of the process of graft copolymerization of styrene, microstructure and quality indicators of the synthesized samples of impact-resistant polystyrene was studied. It is testifi ed that an increase in the molecular mass of the elastomer does not aff ect the monomer conversion, however, it leads to a phase inversion shifting to the region of lower conversion degrees of styrene. In this case, an increase in the size of rubber particles and an increase in the content of the gel fraction are observed in the copolymer. The established changes in the microstructure correlate with the properties of high-impact polystyrene.


Polymers ◽  
2021 ◽  
Vol 13 (6) ◽  
pp. 901
Author(s):  
Miklós Berczeli ◽  
Zoltán Weltsch

The development of bonding technology and coating technologies require the use of modern materials and topologies for the demanding effect and modification of their wetting properties. For the industry, a process modification process that can be integrated into a process is the atmospheric pressure of air operation plasma surface treatment. This can be classified and evaluated based on the wettability, which has a significant impact on the adhesive force. The aim is to improve the wetting properties and to find the relationship between plasma treatment parameters, wetting, and adhesion. High Impact PolyStyrene (HIPS) was used as an experimental material, and then the plasma treatment can be treated with various adjustable parameters. The effect of plasma parameters on surface roughness, wetting contact angle, and using Fowkes theory of the surface energy have been investigated. Seven different plasma jet treatment distances were tested, combined with 5 scan speeds. Samples with the best plasma parameters were prepared from 25 mm × 25 mm overlapping adhesive joints using acrylic/cyanoacrylate. The possibility of creating a completely hydrophilic surface was achieved, where the untreated wetting edge angle decreased from 88.2° to 0° for distilled water and from 62.7° to 0° in the case of ethylene glycol. The bonding strength of High Impact PolyStyrene was increased by plasma treatment by 297%.


1994 ◽  
Vol 12 (6) ◽  
pp. 529-550 ◽  
Author(s):  
Ramazan Benrashid ◽  
Gordon L. Nelson ◽  
Donald J. Ferm

Samples of m-PPO (virgin and flame retarded) and high impact polystyrene blended with zinc and zinc borate (2ZnO·3B2O3·3.5H 2O), were pre pared. The effect of triaryl phosphate on the flame retardancy of PPO-HIPS in conjunction with zinc and zinc borate was studied. For polystyrene zinc borate shows some reduction in smoke generation. Zinc, however does not show any effect on smoke generation for high impact polystyrene. Triphenyl phosphate shows minimal flame retardancy in HIPS which is not enhanced by zinc. Addition of zinc gives an increase in oxygen index for FR m-PPO, whereas zinc borate decreases the OI values. Zinc borate may sequester triaryl phos phate and thus eliminate its vapor phase activity. Zinc borate shows a signifi cant reduction in smoke generation and rate of heat release for m-PPO.


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