Radiation-grafting of ethylene glycol dimethacrylate (EGDMA) and glycidyl methacrylate (GMA) onto silicone rubber

2016 ◽  
Vol 127 ◽  
pp. 21-26 ◽  
Author(s):  
G.G. Flores-Rojas ◽  
E. Bucio
RSC Advances ◽  
2014 ◽  
Vol 4 (81) ◽  
pp. 42965-42970 ◽  
Author(s):  
Lin Zhou ◽  
Xiaoxiao Li ◽  
Yong Wang ◽  
Mei Hong ◽  
Yongye Liang ◽  
...  

A monodisperse Pt/ceria hybrid with controlled nanoporous structure was fabricated with the aid of poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) microspheres as a hard template.


2018 ◽  
Vol 81 (11) ◽  
pp. 1467-1474 ◽  
Author(s):  
Florian Meischl ◽  
Klemens Losso ◽  
Christian G. Kirchler ◽  
Stefan E. Stuppner ◽  
Christian W. Huck ◽  
...  

2014 ◽  
Vol 79 (10) ◽  
pp. 1249-1261 ◽  
Author(s):  
Sanja Marinovic ◽  
Aleksandra Milutinovic-Nikolic ◽  
Aleksandra Nastasovic ◽  
Marija Zunic ◽  
Zorica Vukovic ◽  
...  

Macroporous nanocomposite of poly (glycidyl methacrylate-co-ethylene glycol dimethacrylate) and acid modified bentonite was prepared by radical suspension copolymerization. Nanocomposite was functionalized with diethylene triamine (deta), by ring-opening reaction of the pendant epoxy groups. Functionalization was performed in order to enable phenol derivatives sorption. This new, not sufficiently investigated material, with developed porous structure was denoted CP-SA-deta. In this study, the influence of temperature on 4-nitrophenol (4NP) sorption on CP-SA-deta was investigated. The chemisorption was estimated as dominant process since activation energy of sorption of 4NP of 54.8 kJ mol-1 was obtained. After determining the optimal sorption conditions for 4NP, the sorption of 2-nitrophenol (2NP) and 2-chloro 4-nitrophenol (2Cl4NP) on CP-SA-deta was investigated with respect to pH, initial concentration and contact time. The 2NP sorption was seldom tested, while according to our knowledge, the 2Cl4NP sorption was not investigated. The isotherm data were best fitted with Langmuir model, while the sorption dynamics obeyed the pseudo-second-order kinetic model for all derivatives.


2020 ◽  
Vol 23 (3) ◽  
Author(s):  
Luciana C. Costa ◽  
Rafaela C. Monteiro ◽  
Helena M. A. Castro ◽  
Tatiane S. Ribeiro ◽  
Mirian A. Oliveira ◽  
...  

2004 ◽  
pp. 207-214 ◽  
Author(s):  
Nenad Milosavic ◽  
Radivoje Prodanovic ◽  
Slobodan Jovanovic ◽  
Zoran Vujcic

Glucoamylase was covalently immobilized through the spacer-arm of the poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) spheres by using a glutaraldehyde as a coupling agent. The influence of the enzyme load applied to the support on immobilization, yield and specific activity, has been determined. Obtained specific activity was 700 U/g with immobilization yield of 35 %. The Km value for immobilized glucoamylase was 1.28 % (w/v), pH and temperature optimum were 4.5 and 70?C, respectively. The conversion of 20 % (w/w) starch hydrolysate achieved with the immobilized glucoamylase was 97 % after 5 hours.


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