Fabrication of self-cross-linking fluorinated polyacrylate latex particles with core-shell structure and film properties

2016 ◽  
Vol 104 ◽  
pp. 9-14 ◽  
Author(s):  
Ting Lü ◽  
Dongming Qi ◽  
Dong Zhang ◽  
Qian Liu ◽  
Hongting Zhao
Keyword(s):  
Shell Structure ◽  
Cross Linking ◽  
Core Shell ◽  
Film Properties ◽  
Latex Particles ◽  
Fluorinated Polyacrylate ◽  
Core Shell Structure

Characterization of Fe3O4@CS@NMDP magnetic nanoparticles with core–shell structure prepared by chemical cross-linking method

2017 ◽  
Vol 10 (05) ◽  
pp. 1750056 ◽  
Author(s):  
Huiping Shao ◽  
Jiangcong Qi ◽  
Tao Lin ◽  
Yuling Zhou ◽  
Fucheng Yu
Keyword(s):  
Magnetic Nanoparticles ◽  
Shell Structure ◽  
High Performance ◽  
Cross Linking ◽  
Composite Particles ◽  
Core Shell ◽  
The Core ◽  
Targeting Delivery ◽  
Core Shell Structure ◽  
Chemical Cross Linking

The core–shell structure composite magnetic nanoparticles (NPs), Fe3O4@chitosan@nimodipine (Fe3O4@CS@NMDP), were successfully synthesized by a chemical cross-linking method in this paper. NMDP is widely used for cardiovascular and cerebrovascular disease prevention and treatment, while CS is of biocompatibility. The composite particles were characterized by an X-ray diffractometer (XRD), a Fourier transform infrared spectroscopy (FT-IR), a transmission electron microscopy (TEM), a vibrating sample magnetometers (VSM) and a high performance liquid chromatography (HPLC). The results show that the size of the core–shell structure composite particles is ranging from 12[Formula: see text]nm to 20[Formula: see text]nm and the coating thickness of NMDP is about 2[Formula: see text]nm. The saturation magnetization of core–shell composite NPs is 46.7[Formula: see text]emu/g, which indicates a good potential application for treating cancer by magnetic target delivery. The release percentage of the NMDP can reach 57.6% in a short time of 20[Formula: see text]min in the PBS, and to 100% in a time of 60[Formula: see text]min, which indicates the availability of Fe3O4@CS@NMDP composite NPs for targeting delivery treatment.

Investigation of fluorinated polyacrylate latex with core-shell structure

2005 ◽  
Vol 54 (7) ◽  
pp. 1027-1033 ◽  
Author(s):  
Chaocan Zhang ◽  
Yanjun Chen
Keyword(s):  
Shell Structure ◽  
Core Shell ◽  
Fluorinated Polyacrylate ◽  
Core Shell Structure

Design and Preparation of Rubber Ideal Filler

2006 ◽  
Vol 11-12 ◽  
pp. 525-528 ◽  
Author(s):  
Jian Jun Zhou ◽  
Ya Kang Liu ◽  
Wei Zhao ◽  
You Ping Wu ◽  
Li Qun Zhang
Keyword(s):  
Shell Structure ◽  
Styrene Butadiene Rubber ◽  
Cross Linking ◽  
Core Shell ◽  
Butadiene Rubber ◽  
Seeded Emulsion Polymerization ◽  
Polymeric Particles ◽  
Core Shell Structure ◽  
The Stability ◽  
Styrene Butadiene

Since rubber was applied in people’s normal life, researchers have started to exploit the rubber reinforcing techniques and the relative mechanism. Developing high-effective, simple and economical reinforcing methods and fillers are the emphasis of rubber industry, technology and science. In this paper a rubber ideal filler (IF) is shown. This IF is a kind of composite with core-shell structure which was synthesized by seeded emulsion polymerization. It used styrene (St), polybutadiene oligomer (PBD) as monomers and divinyl benzene (DVB) as cross-linking agent. The effect of the amount of cross-linking agent, concentration of emulsifier and initiator on the stability of the emulsion was studied. The morphology of the latex particles with core-shell structure was characterized by high resolution SEM (ESEM) and DSC (Tg). The results showed that cross-linking polymeric particles exhibited strong reinforcing effect on styrene-butadiene rubber (SBR).

Preparation and properties of novel fluorosilicone thermoplastic vulcanizate with cross-linking-controlled core-shell structure

2019 ◽  
Vol 30 (4) ◽  
pp. 1036-1043 ◽  
Author(s):  
Yanpeng Wang ◽  
Yuan Tang ◽  
Yanrong Ren ◽  
Tao Ding ◽  
Yukun Chen
Keyword(s):  
Shell Structure ◽  
Cross Linking ◽  
Core Shell ◽  
Thermoplastic Vulcanizate ◽  
Core Shell Structure

Preparation of Core/Shell Composite Latex Particles and Toughening Modification for Polyamide 6

2009 ◽  
Vol 79-82 ◽  
pp. 2103-2106
Author(s):  
Xi Jun Liu ◽  
Hai Ping Li ◽  
Feng Li ◽  
Rui Xia Tian ◽  
Qing Li
Keyword(s):  
Shell Structure ◽  
Polyamide 6 ◽  
Core Shell ◽  
Melt Blending ◽  
Seeded Emulsion Polymerization ◽  
Latex Particles ◽  
The Core ◽  
Core Shell Structure ◽  
Average Size ◽  
Shell Composite

In this paper, a novel poly(butyl methacry1ate)/poly(methyl methacrylate-itaconic acid)(PBA/P(MMA-ITA)) latex particles with core/shell structure (CSR) was synthesized by the method of pre-emulsion semi-continuous seeded emulsion polymerization. The core/shell structure of CSR was characterized by TEM and confirmed that the average size of CSR particles was about 330 nm and that of PBA core was about 290 nm. The polyamide 6 (PA 6)/CSR blends (N/CSR) were prepared by the melt-blending technique, and its impact strength reached 40kJ•m-2 (more than 7 times higher than neat PA 6) when the ITA dosage was in the range of 4%~10%. The results of SEM showed that the high toughness of N/CSR blends was the result of the shear deformation of PA 6 matrix induced by cavitation of dispersed phase CSR.

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