scholarly journals Degradation of 4-aminoantipyrine by electro-oxidation with a boron-doped diamond anode: Optimization by central composite design, oxidation products and toxicity

2018 ◽  
Vol 631-632 ◽  
pp. 1079-1088 ◽  
Author(s):  
Lucas de Melo da Silva ◽  
Fábio Gozzi ◽  
Ignasi Sirés ◽  
Enric Brillas ◽  
Silvio Cesar de Oliveira ◽  
...  
2013 ◽  
Vol 34 (8) ◽  
pp. 1043-1051 ◽  
Author(s):  
Geoffroy R.P. Malpass ◽  
Giancarlo R. Salazar-Banda ◽  
Douglas W. Miwa ◽  
Sérgio A.S. Machado ◽  
Artur J. Motheo

2015 ◽  
Vol 33 (1) ◽  
pp. 13-21 ◽  
Author(s):  
H Bouya ◽  
M Errami ◽  
R Salghi ◽  
A Jodeh ◽  
S Messali ◽  
...  

2019 ◽  
Vol 79 (5) ◽  
pp. 921-928 ◽  
Author(s):  
F. Agustina ◽  
A. Y. Bagastyo ◽  
E. Nurhayati

Abstract Electro-oxidation using a boron-doped diamond (BDD) anode can be used as an alternative to leachate treatment. Aside from the hydroxyl radical, BDDs are capable of generating chloride and sulfate radical species that play significant roles in the oxidation of pollutants. This research investigated the role of Cl−:SO42− ions at molar ratios of 237:1, 4:1 and 18:1, and the influence of applied current density (i.e. 50, 75 and 100 mA cm−2) on the removal of organic and ammonium contaminants. The results show that current density had considerable effects on chemical oxygen demand (COD) and colour removal, while ion composition of Cl−:SO42− at pH 3, 5 and 8.5 (original pH) gave different effects on COD and ammonium removal. The pH had a significant effect on the COD removal at the ratio of 237:1, but showed no dramatic effect at the ratio of 18:1, giving ∼40% of COD removal at all pHs tested. This indicates that electro-oxidation at the ratio of 18:1 could be effectively conducted at a wide range of pH. Furthermore, the optimum ammonium removal was obtained at pH 8.5 with the ratio of 237:1. This process was found to be ineffective in increasing the biodegradability index of the leachate; instead, it exhibited mineralization of organic content.


2016 ◽  
Vol 18 (38) ◽  
pp. 26404-26411 ◽  
Author(s):  
Faduma M. Maddar ◽  
Robert A. Lazenby ◽  
Anisha N. Patel ◽  
Patrick R. Unwin

NADH electro-oxidation is faster, but more prone to fouling, at HOPG compared to pBDD.


2020 ◽  
Vol 313 ◽  
pp. 113556
Author(s):  
Mostafa Leili ◽  
Nasrin Shirmohammadi Khorram ◽  
Kazem Godini ◽  
Ghasem Azarian ◽  
Rahim Moussavi ◽  
...  

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