Immobilization of lead by amendments in a mine-waste impacted soil: Assessing Pb retention with desorption kinetic, sequential extraction and XANES spectroscopy

Author(s):  
Frederico Prestes Gomes ◽  
Matheus Sampaio C. Barreto ◽  
Aziz Amoozegar ◽  
Luís Reynaldo Ferracciú Alleoni
Minerals ◽  
2018 ◽  
Vol 8 (9) ◽  
pp. 403 ◽  
Author(s):  
Shinji Matsumoto ◽  
Hirotaka Ishimatsu ◽  
Hideki Shimada ◽  
Takashi Sasaoka ◽  
Ginting Kusuma

Characterization of mine waste rocks and prediction of acid mine drainage (AMD) play an important role in preventing AMD. Although high-tech analytical methods have been highlighted for mineral characterization and quantification, simple testing methods are still practical ways to perform in a field laboratory in mines. Thus, this study applied some simple testing methods to the characterization of mine wastes and AMD prediction in addition to a leaching test and the sequential extraction test with HCl, HF, and HNO3, which have not been applied for these purposes, focusing on the form of sulfur and the neutralization effects of carbonates. The results of the Acid Buffering Characteristic Curve test supported the changing trend of the pH attributing carbonates only during the first 10 leaching cycles in the leaching test. The change in the Net Acid Generating (NAG) pH in the sequential NAG test reflected the solubility of sulfur in the rocks, providing information on the form of sulfur in the rocks and the acid-producing potential over time. Consequently, the sequential NAG test and sequential extraction with the acids in combination with the current standards tests (Acid Base Accounting and NAG tests) provided important information for preventing AMD.


2020 ◽  
Vol 12 (4) ◽  
pp. 1480
Author(s):  
Min-Suk Kim ◽  
Sang-Hwan Lee ◽  
Jeong-Gyu Kim

Arsenic (As) contamination in abandoned mining areas has been of concern in Korea; hence, the reclamation and restoration of these areas must be conducted. Since large contaminated areas have not been restored yet, post management of restoration sites would be insufficient. The aim of this study was to monitor the pollution of environments near the waste dam in mining areas and to assess the fraction and mobility of As. Chemical assessment was conducted using sequential extraction and single extraction methods [Mehlich-3, 1N HCl, the simple bioavailability extraction test (SBET), and the synthetic precipitation leaching procedure (SPLP)], whereas biological assessment was conducted with a bok choy (Brassica campestris L. ssp. chinensis Jusl.) cultivation experiment. The results showed that the waste rock soil, forest soil, and sediments near the dam were contaminated with As. As a result of sequential extraction, most of the As in the soil of the upper part of the dam were observed to be tightly adsorbed (well-crystallized hydrous metal oxides and residual phases), whereas As in the forest soil of the lower part of the dam were observed to be relatively weakly bound (amorphous and poorly-crystallized hydrous metal oxides). These results show that As could be re-dissolved from secondary contaminated forest soil and spread to nearby environments. For the sustainable management of soil environment, an assessment of the fraction and mobility of As coupled with continuous monitoring are required.


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